Article
Polymer Science
Yi-Hsuan Huang, Yu-Chun Wu
Summary: This study explores a low-cost and sustainable adsorbent for the removal of radioactive ions Sr2+ and Co2+ in nuclear wastewater. It is found that alkali-activated metakaolin soaked for 3 days exhibits the optimal adsorption performance. The sorption mechanisms are determined to be ion exchange for Sr2+ and a combination of surface complexation and ion exchange for Co2+. Furthermore, the adsorbent shows selective adsorption towards divalent ions.
Article
Environmental Sciences
Shuting Zhuang, Kunkun Zhu, Lejin Xu, Jun Hu, Jianlong Wang
Summary: In this study, a novel fibrous chitosan biosorbent was prepared using a specific spinning solvent, which exhibited higher adsorption capacity and faster adsorption rate for Co2+ and Sr2+ compared to spherical chitosan. The improvement in adsorption performance was attributed to the higher specific surface area and increased exposure degree of functional groups.
SCIENCE OF THE TOTAL ENVIRONMENT
(2022)
Article
Chemistry, Physical
Shuting Zhuang, Qian Zhang, Jianlong Wang
Summary: This study reported a cost-effective and efficient adsorbent EDTA-chitosan for the removal of Co2+ and Sr2+ from water and wastewater, with explored adsorption behavior and mechanism. The adsorbent showed a high adsorption capacity and affinity towards the nuclides in multicomponents system.
JOURNAL OF MOLECULAR LIQUIDS
(2021)
Article
Energy & Fuels
Reyna Ojeda-Lopez, Enrique Vilarrasa-Garcia, Diana C. S. Azevedo, Carlos Felipe, Juan A. Cecilia, Enrique Rodriguez-Castellon
Summary: The CO2 selectivity in CO2:CH(4) and CO2:N-2 mixtures has been studied in carbon materials with different morphologies and properties. The results show that carbon microfibers have higher CO2 adsorption capacity and selectivity, especially at higher pressures. They also exhibit better CO2 selectivity in CO2:CH4 mixtures. These findings suggest that carbon microfibers are a promising material for CO2 capture and separation.
Article
Engineering, Chemical
Kai Wu, Qing Ye, Lanyang Wang, Fanwei Meng, Hongxing Dai
Summary: This study reports on the nanocomposites of graphene oxide-doped stearate-intercalated layered double oxides as a type of CO2 adsorbents at medium temperatures. The doping of graphene oxide improves the stability and CO2 adsorption capacity of the composite material. The nanocomposites show high surface area and basic site amount, allowing for chemical adsorption of CO2 in the form of carbonate. The 6GO LDO-SA nanocomposite exhibits high regeneration efficiency and fast kinetics.
SEPARATION AND PURIFICATION TECHNOLOGY
(2022)
Article
Engineering, Environmental
Rini K. Vishwakarma, Pavan K. Narayanam, R. Umamaheswari, S. R. Polaki
Summary: Graphene oxide (GO) membranes were functionalized with nitrogen groups through exposure to NH3 vapours, resulting in enhanced Sr adsorption capacity. The NH3 treatment introduces amine, amide, and ammonium functionalities, which react with Sr2+ ions to form complexes. The nitrogen functionalization improves Sr adsorption regardless of the exposure duration and GO precursor type. These NH3-treated GO membranes exhibit optimum Sr adsorption performance, reusable for at least nine cycles, and can release 35-60% of adsorbed Sr. This study demonstrates an energy-efficient solid state membrane-based procedure for selective Sr separation, and provides a platform for separating toxic elements with affinity for N-groups.
JOURNAL OF WATER PROCESS ENGINEERING
(2023)
Article
Chemistry, Physical
Iwona Pelech, Daniel Sibera, Piotr Staciwa, Ewelina Kusiak-Nejman, Joanna Kapica-Kozar, Agnieszka Wanag, Urszula Narkiewicz, Antoni W. Morawski
Summary: This study synthesized ZnO/carbon sphere composites using resorcinol-formaldehyde resin and zinc nitrate. The results showed that the presence of zinc oxide in the carbon matrix had almost no effect on CO2 adsorption capacity, and only decreased when the weight ratio of carbon:zinc was 2:1. Additionally, CO2 adsorption experiments at 40°C revealed that the material with the highest zinc nitrate content as ZnO precursor achieved the highest CO2 adsorption capacity.
Article
Engineering, Environmental
Md Osim Aquatar, Juili S. Mankar, Urvashi Bhatia, Sadhana S. Rayalu, Reddithota J. Krupadam
Summary: Highly efficient CO2 capture at elevated temperatures has been achieved using few-layered graphene nanosheets prepared from solid waste from high energy explosive materials industry. The materials demonstrated high adsorption capacity, selectivity towards CO2, fast adsorption kinetics, and recycling stability, making them promising for real-life CO2 capture applications.
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
(2021)
Article
Chemistry, Physical
Cheng-May Fung, Boon-Junn Ng, Chen-Chen Er, Xin Ying Kong, Lling-Lling Tan, Abdul Rahman Mohamed, Siang-Piao Chai
Summary: Photocatalysis, resembling natural photosynthesis, offers a sustainable solution to environmental threats and energy crisis. The design of a dual Z-scheme photocatalytic system using mixed-phase red/black phosphorus and tungsten oxide effectively enhanced CO2 reduction. The ternary composite material showed enhanced optical absorption capacity and achieved a significant CH4 yield under visible light illumination, surpassing the performance of pristine counterparts. The formation of a dual Z-scheme system and the unique hetero-homo junctions contributed to improved photoconversion performance.
ACS APPLIED ENERGY MATERIALS
(2022)
Article
Materials Science, Multidisciplinary
Nadir Ali, Aijaz Ahmed Babar, Xianfeng Wang, Jianyong Yu, Bin Ding
Summary: A facile strategy to fabricate porous, hollow, and flexible carbon nanofibers (CNF) for enhanced CO2 adsorption is reported in this study. The optimized CNF exhibits exceptional CO2 capture performance and high gas selectivity.
ADVANCED ENGINEERING MATERIALS
(2023)
Article
Chemistry, Multidisciplinary
Jiguang Zhang, Yuting Guo, Bin Shang, Tingting Fan, Xinyi Lian, Pingping Huang, Yunyun Dong, Zhou Chen, Xiaodong Yi
Summary: A g-C3N4-supported Cu2O composite was fabricated in this study, which showed efficient and stable reduction of carbon dioxide to ethylene, providing a promising strategy for reducing carbon dioxide emissions and producing high value-added chemicals.
Article
Chemistry, Inorganic & Nuclear
Hong-Juan Lv, Shu-Cong Fan, Yu-Cheng Jiang, Shu-Ni Li, Quan-Guo Zhai
Summary: Efficient CO2 capture and conversion techniques are essential for global sustainable development. In this study, a novel bi-microporous Sc-MOF was designed and used for CO2 storage and catalytic conversion. The material showed high adsorption selectivity, large CO2 storage capacity, and high catalytic activity.
INORGANIC CHEMISTRY FRONTIERS
(2023)
Article
Chemistry, Physical
Maria Yaseen, Haopeng Jiang, Jinhe Li, Xiaohui Yu, M. Ashfaq Ahmad, Rai Nauman Ali, Lele Wang, Juan Yang, Qinqin Liu
Summary: Photocatalytic CO2 reduction using a CeO2/WO3 Z-scheme heterojunction was investigated in this study. The Z-scheme provided an interfacial free charge carrier and oxygen vacancies as active sites, leading to a significant increase in the CO2 photoconversion activity compared to pristine CeO2. The enhanced light absorption, low defective surface, and slow charge recombination rate in the composite contributed to the improved CO2 reduction efficiency.
APPLIED SURFACE SCIENCE
(2023)
Article
Multidisciplinary Sciences
Farnoush Fathalian, Sepehr Aarabi, Ahad Ghaemi, Alireza Hemmati
Summary: Designing a model to connect CO2 adsorption data with various adsorbents based on graphene oxide (GO) produced from solid biomass, this study aims to develop a machine learning model for predicting the CO2 adsorption capacity. Extracting information from 17 articles, the study considers specific surface area, pore volume, temperature, and pressure as input parameters and CO2 uptake capacity as the model response. Multiple machine learning models, such as support vector machine and random forest, were employed to estimate the adsorption capacity, with the MLP-based ANN showing the best performance.
SCIENTIFIC REPORTS
(2022)
Article
Chemistry, Physical
Jianfei Xiao, Yuan Wang, Tian C. Zhang, Shaojun Yuan
Summary: A novel porous carbon material derived from glucose and dicyandiamide incorporated with reduced graphene oxide was prepared for CO2 capture and supercapacitors, showing great potential for both applications due to its large surface area, nitrogen doping, and high CO2 capture ability.
JOURNAL OF ALLOYS AND COMPOUNDS
(2021)
Article
Engineering, Environmental
Xia Liu, Ju Sun, Xuetao Xu, Ahmed Alsaedi, Tasawar Hayat, Jiaxing Li
CHEMICAL ENGINEERING JOURNAL
(2019)
Article
Chemistry, Analytical
Dadong Shao, Xinghao Liu, Tasawar Hayat, Jiaxing Li, Xuemei Ren
JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY
(2019)
Article
Chemistry, Multidisciplinary
Huihui Gao, Ruya Cao, Xuetao Xu, Jiayou Xue, Shouwei Zhang, Tasawar Hayat, Njud S. Alharbi, Jiaxing Li
ACS SUSTAINABLE CHEMISTRY & ENGINEERING
(2019)
Article
Chemistry, Physical
Ju Sun, Xia Liu, Fengsong Zhang, Jian Zhou, Jin Wu, Ahmed Alsaedi, Tasawar Hayat, Jiaxing Li
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
(2019)
Article
Environmental Sciences
Xia Liu, Ju Sun, Xuetao Xu, Guodong Sheng, Yubing Sun, Yongshun Huang, Ahmed Alsaedi, Tasawar Hayat, Jiaxing Li
ENVIRONMENTAL POLLUTION
(2019)
Article
Engineering, Environmental
Shengxia Duan, Lishun Wu, Jiaxing Li, Yongshun Huang, Xiaoli Tan, Tao Wen, Tasawar Hayat, Ahmed Alsaedi, Xiangke Wang
JOURNAL OF HAZARDOUS MATERIALS
(2019)
Article
Chemistry, Physical
Huihui Gao, Ruya Cao, Xuetao Xu, Shouwei Zhang, Yongshun Huang, Hongcen Yang, Xiaolong Deng, Jiaxing Li
APPLIED CATALYSIS B-ENVIRONMENTAL
(2019)
Article
Chemistry, Multidisciplinary
Xia Liu, Jin Wu, Shouwei Zhang, Congcong Ding, Guodong Sheng, Ahmed Alsaedi, Tasawar Hayat, Jiaxing Li, Yuntao Song
ACS SUSTAINABLE CHEMISTRY & ENGINEERING
(2019)
Article
Chemistry, Physical
Jin Wu, Jian Zhou, Shouwei Zhang, Ahmed Alsaedi, Tasawar Hayat, Jiaxing Li, Yuntao Song
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2019)
Article
Engineering, Environmental
Shouwei Zhang, Huihui Gao, Xuetao Xu, Ruya Cao, Hongcen Yang, Xijin Xu, Jiaxing Li
CHEMICAL ENGINEERING JOURNAL
(2020)
Article
Engineering, Environmental
Kezhu Xu, Jin Wu, Qunling Fang, Linfeng Bai, Jinyu Duan, Jiaxing Li, Huajian Xu, Ailing Hui, Lingyun Hao, Shouhu Xuan
CHEMICAL ENGINEERING JOURNAL
(2020)
Article
Engineering, Environmental
Jian Zhou, Hongjian Zhou, Yingzi Zhang, Jin Wu, Haiming Zhang, Guozhong Wang, Jiaxing Li
CHEMICAL ENGINEERING JOURNAL
(2020)
Article
Chemistry, Analytical
Jin Wu, Yingzi Zhang, Jian Zhou, Ruya Cao, Chengming Wang, Jiaxing Li, Yuntao Song
Summary: A stable and highly efficient adsorbent, UiO-66-NH-SO3H-3, was successfully fabricated using a facile and scalable tactic, showing significant removal capacities for Sr2+ and Cs+. Due to the -SO3H functional groups, this adsorbent can selectively remove Sr2+ and Cs+ even in the presence of different coexisting ions, suggesting potential applications in water treatment.
JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY
(2021)
Review
Environmental Sciences
De Wang, Jianfeng Zhang, Ruya Cao, Yingzi Zhang, Jiaxing Li
Summary: This review provides a comprehensive overview of analytical methods for studying the interaction between graphene oxide (GO) and natural colloids, highlighting the influence of relevant environmental factors.
SCIENCE OF THE TOTAL ENVIRONMENT
(2022)
Article
Engineering, Environmental
De Wang, Jianfeng Zhang, Jiaxing Li
Summary: In this study, a phosphate-functionalized magnetic calcium alginate hydrogel was successfully synthesized, showing high adsorption capacity for uranium contaminants. The study also validates a promising green engineering soil remediation technology that effectively removes radioactive substances from soil.
CHEMICAL ENGINEERING JOURNAL
(2023)