4.6 Article

A New Application of a Mesoporous Hybrid of Tungsten Oxide and Carbon as an Adsorbent for Elimination of Sr2+ and Co2+ from an Aquatic Environment

期刊

ACS SUSTAINABLE CHEMISTRY & ENGINEERING
卷 6, 期 2, 页码 2462-2473

出版社

AMER CHEMICAL SOC
DOI: 10.1021/acssuschemeng.7b03818

关键词

Tungsten oxide and carbon; Sr2+; Co2+; adsorption

资金

  1. National Natural Science Foundation of China [21677146]
  2. Jiangsu Provincial Key Laboratory of Radiation Medicine and Protection
  3. Priority Academic Program Development of Jiangsu Higher Education Institutions

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The mesoporous tungsten oxide and carbon (WOx/C) nanowire network was successfully synthesized using an environmentally friendly solvothermal method. The as-prepared composite was applied as an adsorbent for metal ion elimination from wastewater via batch experiments. The adsorption results suggested that the adsorption interactions between WOx/C and Sr2+ and Co2+ were pH-dependent, while the effect of ionic strength toward sorption capacity depended on the solution acidity and adsorbates. The sorption process followed the Langmuir model with the maximum sorption capacity of Sr2+ and Co2+ onto WOx/C being 175.0 and 326.0 mg/g at 308 K, respectively. Thermodynamic parameters, namely, Delta S degrees, Delta H degrees, and Delta G degrees, indicated an endothermic, but spontaneous adsorption process. All the exhibited results demonstrated that the as-synthesized WOx/C nanowire network has the potential to be an effective adsorbent for heavy metal ion remediation from aqueous solutions.

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