期刊
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
卷 2015, 期 11, 页码 2517-2523出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201403590
关键词
Asymmetric synthesis; Cyclization; Oxygen heterocycles; Small ring systems; Epoxides
资金
- Council of Scientific and Industrial Research (CSIR), New Delhi
- Indian Institute of Technology (IIT), Ropar
- Department of Science and Technology (DST), New Delhi [SR/FT/CS-84/2010]
A Lewis-acid-catalysed tandem Meinwald rearrangement/[3+2]-cycloaddition of epoxides with donor-acceptor cyclopropanes to synthesize varieties of cis-2,5-aryl-benzyl-substituted tetrahydrofurans is described. An enantioselective version of the same transformation was achieved using an InCl3-PyBOX catalyst system.
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