期刊
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
卷 2015, 期 6, 页码 1309-1313出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201403508
关键词
Synthetic methods; Heterogeneous catalysis; Nanoparticles; Oxidation; Copper; Anhydrides; Peroxides
资金
- Department of Science and Technology (DST), New Delhi [SB/S1/OC-53/2013]
- Council of Scientific and Industrial Research (CSIR), New Delhi [02(0096)/12/EMR-II]
- CSIR
An elegant synthesis of carboxylic acid anhydrides has been developed directly from arylaldehydes using CuO nanoparticles as the catalyst and tert-butyl hydroperoxide (TBHP) as the oxidant. During anhydride formation the reaction proceeds through a double sp(2) C-H functionalization of aldehydes to generate two consecutive C-O bonds.
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