期刊
JOURNAL OF SAUDI CHEMICAL SOCIETY
卷 21, 期 4, 页码 450-457出版社
ELSEVIER
DOI: 10.1016/j.jscs.2016.03.008
关键词
Metal; Nanoparticles; Natural products; Catalysis; Suzuki
资金
- King Saud University, Deanship of Scientific Research, College of Science, Research Center
Green and eco-friendly synthesis of palladium nanoparticles NPs is carried out under facile and eco-friendly conditions using an aqueous solution of Salvadora persica L. (SP) root extract (RE) as a bioreductant, which is commonly known as Miswak. The as-synthesized Pd NPs were characterized using various spectroscopic and microscopic techniques, including, UV-Vis spectroscopy, FT-IR spectroscopy, XRD, ICP-MS and TEM. Detailed investigations of the Pd NPs have confirmed that the polyphenolic phytomolecules present in the RE of Miswak not only act as a bioreductant by facilitating the reduction and growth of Pd NPs, but they also functionalize the surface of Pd NPs and stabilized them in various solvents. Furthermore, the catalytic activity of the green synthesized Pd NPs was also tested toward the Suzuki coupling reactions of various aryl halides in aqueous media. The as-prepared Pd NPs exhibited superior catalytic activity and reusability for the Suzuki coupling reaction in aqueous and aerobic conditions. The kinetics of the reaction studied by GC revealed that the conversion of various aryl halides to biphenyl takes place in a short time. (C) 2016 King Saud University. Production and hosting by Elsevier B.V.
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