期刊
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
卷 2015, 期 13, 页码 2972-2977出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201500086
关键词
Synthetic methods; Alkylation; Alcohols; Amines; Cesium; Oxygen
资金
- Natural Science Foundation of Jiangsu Province of China [BK20130294]
- Young National Natural Science Foundation of China [21402133]
- Priority Academic Program Development of Jiangsu Higher Education Institution (PAPD)
- Qing Lan Project
A highly efficient and practical transition-metal-free CsOH/O-2 catalyst system was developed for the N-alkylation of amines with alcohols under argon. This strategy was compatible with many alcohols and exhibits excellent functional group tolerance. More significantly, the selective formation of secondary amines was achieved in excellent yields. The detailed mechanistic study gave a clear understanding of the role of base and oxygen in the catalytic cycle.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据