4.3 Article

Design of Research on Performance of a New Iridium Coordination Compound for the Detection of Hg2+

出版社

MDPI
DOI: 10.3390/ijerph14101232

关键词

heavy metal; iridium coordination compound; new auxiliary ligands; quantum efficiency; sustainability; green environment

资金

  1. Zhejiang Provincial Natural Science Foundation [LY14F030005]
  2. Zhejiang Provincial Science and Technology Project [2015C31160]
  3. Lishui High-level Personnel Project [2015RC04]
  4. Zhongshan City Science and Technology Bureau [2017B1015]

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Heavy metal pollution has become one of the most significant pollution problems encountered by our country in terms of environment protection. In addition to the significant effects of heavy metals on the human body and other organisms through water, food chain enrichment and other routes, heavy metals involved in daily necessities beyond the level limit could also affect people's lives, so the detection of heavy metals is extremely important. Ir (III) coordination compound, considered to be one of the best phosphorescent sensing materials, is characterized by high luminous efficiency, easy modification of the ligand and so on, and it has potential applications in the field of heavy metal detection. This project aims to product a new Ir (III) functional coordination compound by designing a new auxiliary ligand and a main ligand with a sulfur identification unit, in order to systematically investigate the application of iridium coordination compound in the detection of the heavy metal Hg2+. With the introduction of the sulfur identification unit, selective sensing of Hg2+ could be achieved. Additionally, a new auxiliary ligand is also introduced to produce a functional iridium coordination compound with high quantum efficiency, and to diversify the application of iridium coordination compound in this field.

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