期刊
RSC ADVANCES
卷 7, 期 6, 页码 3443-3449出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6ra26811k
关键词
-
资金
- Intercollegiate Key Scientific Research Projects of Henan Province [15A150065, 15A150018]
The Pd/SBA-15 catalyst was synthesised through the reduction of PdCl2 by the surface-bonded vinyl group on vinyl-functionalized SBA-15, which was prepared via co-polymerization. XRD and XPS characterization confirmed the successful reduction of Pd(II) to Pd(0). Pd/SBA-15 showed a narrow palladium particle-size distribution of about 5-6 nm in the TEM image. The Pd/SBA-15 catalyst was effective for the hydrogenation of aromatic nitro compounds with zero-order kinetics, and the TOF for the hydrogenation of nitrobenzene was 1124 h(-1) at 313 K and 1 atm H-2. A steric effect was observed for the substituted nitroarenes.
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