期刊
RSC ADVANCES
卷 7, 期 67, 页码 42168-42171出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7ra08784e
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资金
- Sasol Ltd (South Africa)
- NRF
- THRIP
- University of Johannesburg
- University of Technology Sydney
Benzylic and allylic alcohols are rendered electrophilic without chemical modification by the use of aluminium triflate as catalyst. The reaction succeeds with alcohol, thiol, carbon and nitrogen nucleophiles. When phenols are employed as nucleophiles, C-alkylation ensues. An advanced application of the method is demonstrated in the synthesis of 2H-chromenes and their N and S analogues.
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