期刊
RSC ADVANCES
卷 7, 期 12, 页码 7130-7139出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6ra27126j
关键词
-
资金
- National Natural Science Foundation of China [21673290, 21376261, 21503273]
- 863 Program of China [2015AA034603]
A series of Mox-Fe/beta catalysts with constant Fe and variable Mo content were synthesized and investigated for selective catalytic reduction (SCR) of NOx with NH3. It was found that the Mo-0.2-Fe/beta catalyst exhibited excellent activity, N-2 selectivity and preferable resistance to H2O and SO2. The Mo-x-Fe/ beta catalysts were characterized by various analytical techniques. TEM and SEM images showed that the addition of Mo could enhance the dispersion of iron oxides. The results of NH3-TPD and Py-IR indicated that the introduction of Mo resulted in a change of Bronsted acidity, which was associated with high-temperature SCR activity. XPS and XANES results showed that the introduction of Mo resulted in a change of Fe2+ content, which determined the low-temperature activity. DFT calculations showed the strong effects of Mo on the crystal structure, charge distribution and oxygen vacancy formation energy of iron oxides, which further explained the role of Mo in the catalyst behaviors during the SCR process.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据