4.5 Article

Luminescent Polythiophene-Based Main-Chain Polyoxometalate-Containing Conjugated Polymers with Improved Solar-Cell Performance

期刊

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
卷 -, 期 4, 页码 656-663

出版社

WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejic.201402839

关键词

Polyoxometalates; Polymers; Molecular devices; Conducting materials; Solar cells

资金

  1. National Science Foundation (NSF) [DMR1308577]
  2. Direct For Mathematical & Physical Scien
  3. Division Of Materials Research [1308577] Funding Source: National Science Foundation

向作者/读者索取更多资源

New polythiophene-based hybrid conjugated polymers (P2 and P3) containing different amounts of hexamolybdate clusters, which are covalently embedded in the main chain, were successfully synthesized by using the Stille coupling reaction. These soluble hybrid polymers show absorptions in the 400-550 nm range in dilute solutions, which extend beyond 700 nm in thin films. The hybrid polymers are moderately fluorescent in dilute solutions, and the embedded polyoxometalates only partially quench the backbone fluorescence. Simple single-layer photovoltaic cells with a device configuration of ITO/PEDOT:PSS/(P2 or P3)/Ca/Al were fabricated, and a power conversion efficiency of 0.24% was obtained for P2, which is among the highest values reported for POM-containing hybrid polymers including hybrid diblock copolymers.

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