期刊
CATALYSIS SCIENCE & TECHNOLOGY
卷 7, 期 4, 页码 5833-5837出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7cy01772c
关键词
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资金
- Italian MIUR through the PRIN Project SMARTNESS [2015K7FZLH]
- Fondazione CR Firenze
Pyridine decorated multi-walled carbon nanotubes (N-Py-MW) have been successfully employed as a catalyst for the reduction of carbon dioxide to methyl borinate (R2BO-CH3) in the presence of 9-borabicyclo.3.3.1] nonane. N-Py-MW represents the first example of a heterogeneous, metal-free and durable catalyst for CO2 hydroboration to methanol. A mechanistic cycle has been proposed on the basis of targeted blank experiments and a quantum chemical study, highlighting the non-innocent role played by the nanotube carrier in the final N-Py-MW catalytic performance.
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