期刊
ACS CATALYSIS
卷 7, 期 7, 页码 4446-4450出版社
AMER CHEMICAL SOC
DOI: 10.1021/acscatal.7b01316
关键词
arenols; phenanthroline backbone; PN3-pincer; hydrogenation; catalysis
资金
- King Abdullah University of Science and Technology (KAUST)
Selective catalytic hydrogenation of aromatic compounds is extremely challenging using transition-metal catalysts. Hydrogenation of arenols to substituted tetrahydronaphthols or cyclohexanols has been reported only with heterogeneous catalysts. Herein, we demonstrate the selective hydrogenation of arenols to the corresponding tetrahydronaphthols or cyclohexanols catalyzed by a phenanthroline-based PN3-ruthenium pincer catalyst.
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