4.8 Article

Generalized laws of thermodynamics in the presence of correlations

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NATURE COMMUNICATIONS
卷 8, 期 -, 页码 -

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NATURE PUBLISHING GROUP
DOI: 10.1038/s41467-017-02370-x

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资金

  1. European Commission (FETPRO QUIC (H2020-FET-PROACT)) [641122]
  2. European Commission (FETPRO QUIC STREP EQuaM)
  3. European Commission (FETPRO QUIC STREP RAQUEL)
  4. European Research Council (AdG OSYRIS)
  5. European Research Council (AdG IRQUAT)
  6. Spanish MINECO [FIS2008-01236, FIS2013-46768-P FOQUS, FISICATEAMO FIS2016-79508-P]
  7. Spanish MINECO (Severo Ochoa Excellence Grant) [SEV-2015-0522]
  8. FEDER
  9. Generalitat de Catalunya [SGR 874, 875, 966]
  10. CERCA Program/Generalitat de Catalunya
  11. Fundacio Privada Cellex
  12. CELLEX-ICFO-MPQ fellowship

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The laws of thermodynamics, despite their wide range of applicability, are known to break down when systems are correlated with their environments. Here we generalize thermodynamics to physical scenarios which allow presence of correlations, including those where strong correlations are present. We exploit the connection between information and physics, and introduce a consistent redefinition of heat dissipation by systematically accounting for the information flow from system to bath in terms of the conditional entropy. As a consequence, the formula for the Helmholtz free energy is accordingly modified. Such a remedy not only fixes the apparent violations of Landauer's erasure principle and the second law due to anomalous heat flows, but also leads to a generally valid reformulation of the laws of thermodynamics. In this information-theoretic approach, correlations between system and environment store work potential. Thus, in this view, the apparent anomalous heat flows are the refrigeration processes driven by such potentials.

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