期刊
CHEMICAL SCIENCE
卷 8, 期 2, 页码 1056-1061出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6sc03471c
关键词
-
资金
- Swedish Research Council (VR)
- Knut och Alice Wallenbergs Foundation
A new method is presented for 1,3-difluorination and 1,3-oxyfluorination reactions. The process is based on iodonium mediated opening of 1,1-disubstituted cyclopropanes. The reaction proceeds with high chemo and regioselectivity under mild reaction conditions typically at room temperature in a couple of hours. The reaction probably occurs via electrophilic ring-opening of cyclopropanes.
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