Single operation palladium catalysed C(sp3)–H functionalisation of tertiary aldehydes: investigations into transient imine directing groups

Auxiliary-Assisted Palladium-Catalyzed Direct C(sp3)–H Sulfonamidation To Afford 1,2-Amino Alcohol Derivatives

(2017) Yi Dong et al.   JOURNAL OF ORGANIC CHEMISTRY

Diverse ortho-C(sp2)–H Functionalization of Benzaldehydes Using Transient Directing Groups

(2017) Xi-Hai Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pd-Catalyzed Direct ortho-C–H Arylation of Aromatic Ketones Enabled by a Transient Directing Group

(2017) Jiancong Xu et al.   ORGANIC LETTERS

Synthesis of Fluorenones from Benzaldehydes and Aryl Iodides: Dual C–H Functionalizations Using a Transient Directing Group

(2017) Xiao-Yang Chen et al.   ORGANIC LETTERS

Palladium-Catalyzed β-C–H Arylation of Alkyl Carboxamides with Sterically Hindered Aryl Iodides Using ortho-Sulfinyl Aniline Auxiliaries

(2017) Delong Mu et al.   ACS Catalysis

Catalytic C(sp3)−H Arylation of Free Primary Amines with anexoDirecting Group Generated In Situ

(2016) Yan Xu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Buttressing Salicylaldehydes: A Multipurpose Directing Group for C(sp3)−H Bond Activation

(2016) Akira Yada et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Transformations of Alkyl C–H Bonds

(2016) Jian He et al.   CHEMICAL REVIEWS

Bridging C−H Activation: Mild and Versatile Cleavage of the 8-Aminoquinoline Directing Group

(2016) Martin Berger et al.   CHEMISTRY-A EUROPEAN JOURNAL

A simple route to dinuclear complexes containing unusual μ-Nsulfonamidobridges

(2016) Jesús Sanmartín-Matalobos et al.   JOURNAL OF COORDINATION CHEMISTRY

Catalytic C–H Arylation of Aliphatic Aldehydes Enabled by a Transient Ligand

(2016) Ke Yang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pd-Catalyzed γ-C(sp3)–H Arylation of Free Amines Using a Transient Directing Group

(2016) Yongwei Wu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-catalysed transannular C–H functionalization of alicyclic amines

(2016) Joseph J. Topczewski et al.   NATURE

Site-selective and stereoselective functionalization of unactivated C–H bonds

(2016) Kuangbiao Liao et al.   NATURE

Acetohydrazone: A Transient Directing Group for Arylation of Unactivated C(sp3)–H Bonds

(2016) Fei Ma et al.   ORGANIC LETTERS

Functionalization of C(sp3)-H bonds using a transient directing group

(2016) F.-L. Zhang et al.   SCIENCE

The design of a readily attachable and cleavable molecular scaffold for ortho-selective C–H alkenylation of arene alcohols

(2016) Brian J. Knight et al.   Chemical Science

β-Arylation of oxime ethers using diaryliodonium salts through activation of inert C(sp)–H bonds using a palladium catalyst

(2016) Jing Peng et al.   Chemical Science

Undirected, Homogeneous C–H Bond Functionalization: Challenges and Opportunities

(2016) John F. Hartwig et al.   ACS Central Science

Bidentate, Monoanionic Auxiliary-Directed Functionalization of Carbon–Hydrogen Bonds

(2015) Olafs Daugulis et al.   ACCOUNTS OF CHEMICAL RESEARCH

Ligand-Enabled Catalytic CH Arylation of Aliphatic Amines by a Four-Membered-Ring Cyclopalladation Pathway

(2015) Chuan He et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Directed C(sp3)-H Arylation of Saturated Heterocycles at C-3 Using a Concise Optimization Approach

(2015) Dominic P. Affron et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Understanding the Effects of Bidentate Directing Groups: A Unified Rationale for sp2 and sp3 C–H Bond Activations

(2015) Hao Tang et al.   JOURNAL OF ORGANIC CHEMISTRY

Iridium(III)-Catalyzed Direct Arylation of C–H Bonds with Diaryliodonium Salts

(2015) Pan Gao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pd(ii)-Catalyzed arylation of unactivated methylene C(sp3)–H bonds with aryl halides using a removable auxiliary

(2014) Qi Zhang et al.   CHEMICAL COMMUNICATIONS

Regio- and Stereospecific Synthesis of C-3 Functionalized Proline Derivatives by Palladium Catalyzed Directed C(sp3)–H Arylation

(2014) Dominic P. Affron et al.   ORGANIC LETTERS

Regioselective ketone  -alkylation with simple olefins via dual activation

(2014) F. Mo et al.   SCIENCE

Catalytic CC bond forming transformations via direct β-CH functionalization of carbonyl compounds

(2014) Zhongxing Huang et al.   TETRAHEDRON LETTERS

Palladium-catalyzed trifluoroacetate-promoted mono-arylation of the β-methyl group of alanine at room temperature: synthesis of β-arylated α-amino acids through sequential C–H functionalization

(2014) Bo Wang et al.   Chemical Science

Palladium-Catalyzed Direct Functionalization of 2-Aminobutanoic Acid Derivatives: Application of a Convenient and Versatile Auxiliary

(2013) Mengyang Fan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Use of a Readily Removable Auxiliary Group for the Synthesis of Pyrrolidones by the Palladium-Catalyzed Intramolecular Amination of Unactivated γ C(sp3)H Bonds

(2013) Gang He et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Functionalization of C(sp2)H and C(sp3)H Bonds by Using Bidentate Directing Groups

(2013) Guy Rouquet et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

C–H bond activation enables the rapid construction and late-stage diversification of functional molecules

(2013) Joanna Wencel-Delord et al.   Nature Chemistry

CH Bond Functionalization: Emerging Synthetic Tools for Natural Products and Pharmaceuticals

(2012) Junichiro Yamaguchi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Characterization of DMSO Coordination to Palladium(II) in Solution and Insights into the Aerobic Oxidation Catalyst, Pd(DMSO)2(TFA)2

(2012) Tianning Diao et al.   INORGANIC CHEMISTRY

Palladium-catalyzed N-(2-pyridyl)sulfonyl-directed C(sp3)–H γ-arylation of amino acid derivatives

(2012) Nuria Rodríguez et al.   Chemical Science

Carboxylate-Assisted Transition-Metal-Catalyzed C−H Bond Functionalizations: Mechanism and Scope

(2011) Lutz Ackermann   CHEMICAL REVIEWS

Transition metal-catalyzed arylation of unactivated C(sp3)–H bonds

(2011) Olivier Baudoin   CHEMICAL SOCIETY REVIEWS

Palladium-Catalyzed Ligand-Directed C−H Functionalization Reactions

(2010) Thomas W. Lyons et al.   CHEMICAL REVIEWS

Overview of the Mechanistic Work on the Concerted Metallation–Deprotonation Pathway

(2010) David Lapointe et al.   CHEMISTRY LETTERS

Functionalization of Organic Molecules by Transition-Metal-Catalyzed C(sp3)H Activation

(2010) Rodolphe Jazzar et al.   CHEMISTRY-A EUROPEAN JOURNAL

Palladium(II)-Catalyzed CH Activation/CC Cross-Coupling Reactions: Versatility and Practicality

(2009) Xiao Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Pd(0)/PR3-Catalyzed Intermolecular Arylation of sp3C−H Bonds

(2009) Masayuki Wasa et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

O-Acetyl Oximes as Transformable Directing Groups for Pd-Catalyzed C−H Bond Functionalization

(2009) Sharon R. Neufeldt et al.   ORGANIC LETTERS

Dimeric Complexes of a Tridentate Schiff Base Ligand – Crystal Structure of a CuII Complex with Uncommon μ2-Nsulfonamido Bridges and Ferromagnetic Behaviour

(2008) Jesús Sanmartín et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Pd(II)-Catalyzed Cross-Coupling of sp3C−H Bonds with sp2and sp3Boronic Acids Using Air as the Oxidant

(2008) Dong-Hui Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY