期刊
CHEMICAL SCIENCE
卷 8, 期 11, 页码 7359-7367出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7sc03372a
关键词
-
资金
- Swiss National Science Foundation, through the NCCR Molecular Systems Engineering [200021_156063/1]
- Swiss National Science Foundation, through R'Equip [206021_157687]
Some complexes of Cr(III) and Cr(0) have long been known to exhibit interesting photophysical and photochemical properties, but in the past few years important conceptual progress was made. This Perspective focuses on the recent developments of Cr(III) complexes as luminophores and dyes for solar cells, their application in photoredox catalysis, their use as sensitizers in upconversion processes, and their performance as photochemical nitric oxide sources. The example of a luminescent Cr(0) isocyanide complex illustrates the possibility of obtaining photoactive analogues of d(6) metal complexes that are commonly made from precious metals such as Ru(II) or Ir(III). The studies highlighted herein illustrate the favorable excited-state properties of robust first-row transition metal complexes with broad application potential.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据