Harnessing non-covalent interactions to exert control over regioselectivity and site-selectivity in catalytic reactions

Distal Stereocontrol Using Guanidinylated Peptides as Multifunctional Ligands: Desymmetrization of Diarylmethanes via Ullman Cross-Coupling

(2016) Byoungmoo Kim et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ion Pair-Directed Regiocontrol in Transition-Metal Catalysis: A Meta-Selective C–H Borylation of Aromatic Quaternary Ammonium Salts

(2016) Holly J. Davis et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Aspartyl Oxidation Catalysts That Dial In Functional Group Selectivity, along with Regio- and Stereoselectivity

(2016) Joshua S. Alford et al.   ACS Central Science

Undirected, Homogeneous C–H Bond Functionalization: Challenges and Opportunities

(2016) John F. Hartwig et al.   ACS Central Science

Final-Stage Site-Selective Acylation for the Total Syntheses of Multifidosides A-C

(2015) Yoshihiro Ueda et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Total Synthesis of Ellagitannins through Regioselective Sequential Functionalization of Unprotected Glucose

(2015) Hironori Takeuchi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Supramolecular Catalysis in Metal–Ligand Cluster Hosts

(2015) Casey J. Brown et al.   CHEMICAL REVIEWS

Interligand Interactions Dictate the Regioselectivity of trans-Hydrometalations and Related Reactions Catalyzed by [Cp*RuCl]. Hydrogen Bonding to a Chloride Ligand as a Steering Principle in Catalysis

(2015) Stephan M. Rummelt et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A meta-selective C–H borylation directed by a secondary interaction between ligand and substrate

(2015) Yoichiro Kuninobu et al.   Nature Chemistry

Ruthenium-Catalyzedtrans-Selective Hydrostannation of Alkynes

(2014) Stephan M. Rummelt et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Review: A History of Cyclodextrins

(2014) Grégorio Crini   CHEMICAL REVIEWS

Functional group directed C–H borylation

(2014) A. Ros et al.   CHEMICAL SOCIETY REVIEWS

Experimental Lineage and Functional Analysis of a Remotely Directed Peptide Epoxidation Catalyst

(2014) Phillip A. Lichtor et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Beyond Classical Reactivity Patterns: Hydroformylation of Vinyl and Allyl Arenes to Valuable β- and γ-Aldehyde Intermediates Using Supramolecular Catalysis

(2014) Paweł Dydio et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalyst Control over Regio- and Enantioselectivity in Baeyer–Villiger Oxidations of Functionalized Ketones

(2014) David K. Romney et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Supramolecular control of selectivity in transition-metal catalysis through substrate preorganization

(2014) Paweł Dydio et al.   Chemical Science

Recent Developments in Asymmetric Phase-Transfer Reactions

(2013) Seiji Shirakawa et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Supramolecular Control of Selectivity in Hydroformylation of Vinyl Arenes: Easy Access to Valuable β-Aldehyde Intermediates

(2013) Paweł Dydio et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Traceless Directing Group for CH Borylation

(2013) Sean M. Preshlock et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Hydrogen-bond mediated regio- and enantioselectivity in a C–H amination reaction catalysed by a supramolecular Rh(ii) complex

(2013) Thorsten Höke et al.   CHEMICAL COMMUNICATIONS

Supramolecular catalysis. Part 1: non-covalent interactions as a tool for building and modifying homogeneous catalysts

(2013) Matthieu Raynal et al.   CHEMICAL SOCIETY REVIEWS

Supramolecular catalysis. Part 2: artificial enzyme mimics

(2013) Matthieu Raynal et al.   CHEMICAL SOCIETY REVIEWS

Chemical Tailoring of Teicoplanin with Site-Selective Reactions

(2013) Tejas P. Pathak et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric Catalysis at a Distance: Catalytic, Site-Selective Phosphorylation of Teicoplanin

(2013) Sunkyu Han et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Precise Supramolecular Control of Selectivity in the Rh-Catalyzed Hydroformylation of Terminal and Internal Alkenes

(2013) Paweł Dydio et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Computational Study of the Extensive Role of Heterocyclic Ligands in Acetylene Hydration by a Bifunctional Organometallic Catalyst

(2013) Amy J. Arita et al.   ORGANOMETALLICS

Catalytic Selective Synthesis

(2012) Jessada Mahatthananchai et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric Ion-Pairing Catalysis

(2012) Katrien Brak et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric Counteranion-Directed Catalysis: Concept, Definition, and Applications

(2012) Manuel Mahlau et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Site-Selective Bromination of Vancomycin

(2012) Tejas P. Pathak et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Site-Selective Thiocarbonylations and Deoxygenations of Vancomycin Reveal Hydroxyl-Dependent Conformational Effects

(2012) Brandon S. Fowler et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Outer-Sphere Direction in Iridium C–H Borylation

(2012) Philipp C. Roosen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The progression of chiral anions from concepts to applications in asymmetric catalysis

(2012) Robert J. Phipps et al.   Nature Chemistry

Selective transformations of complex molecules are enabled by aptameric protective groups

(2012) Andreas A. Bastian et al.   Nature Chemistry

Combinatorial evolution of site- and enantioselective catalysts for polyene epoxidation

(2012) Phillip A. Lichtor et al.   Nature Chemistry

Removable Directing Groups in Organic Synthesis and Catalysis

(2011) Géraldine Rousseau et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Remote Supramolecular Control of Catalyst Selectivity in the Hydroformylation of Alkenes

(2011) Paweł Dydio et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Regioselectivity of the borylation of alkanes and arenes

(2011) John F. Hartwig   CHEMICAL SOCIETY REVIEWS

Enzymatic functionalization of carbon–hydrogen bonds

(2010) Jared C. Lewis et al.   CHEMICAL SOCIETY REVIEWS

Transition-State Stabilization by a Secondary Substrate-Ligand Interaction: A New Design Principle for Highly Efficient Transition-Metal Catalysis

(2010) Tomáš Šmejkal et al.   CHEMISTRY-A EUROPEAN JOURNAL

Naphthalene Diels−Alder in a Self-Assembled Molecular Flask

(2010) Takashi Murase et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Hydrogen-Bond-Mediated Enantio- and Regioselectivity in a Ru-Catalyzed Epoxidation Reaction

(2010) Philipp Fackler et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Supramolecular catalysis beyond enzyme mimics

(2010) Jurjen Meeuwissen et al.   Nature Chemistry

Attractive noncovalent interactions in asymmetric catalysis: Links between enzymes and small molecule catalysts

(2010) R. R. Knowles et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

C−H Activation for the Construction of C−B Bonds

(2009) Ibraheem A. I. Mkhalid et al.   CHEMICAL REVIEWS

Molecular recognition in Mn-catalyzed C–H oxidation. Reaction mechanism and origin of selectivity from a DFT perspective

(2009) David Balcells et al.   DALTON TRANSACTIONS

A Supramolecular Catalyst for the Decarboxylative Hydroformylation of α,β-Unsaturated Carboxylic Acids

(2008) Tomáš Šmejkal et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

High Turnover Remote Catalytic Oxygenation of Alkyl Groups:  How Steric Exclusion of Unbound Substrate Contributes to High Molecular Recognition Selectivity

(2008) Siddhartha Das et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Finding the Proton in a Key Intermediate ofanti-Markovnikov Alkyne Hydration by a Bifunctional Catalyst

(2008) Douglas B. Grotjahn et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Supramolecular Catalyst for Regioselective Hydroformylation of Unsaturated Carboxylic Acids

(2007) Tomáš Šmejkal et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Molecular recognition in homogeneous transition metal catalysis: a biomimetic strategy for high selectivity

(2007) Siddartha Das et al.   CHEMICAL COMMUNICATIONS