期刊
CHEMICAL SCIENCE
卷 8, 期 3, 页码 2337-2343出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6sc04893e
关键词
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资金
- Natural Sciences and Engineering Research Council of Canada
- Canada Foundation for Innovation (CFI)
A donor-acceptor complex of HBNH was prepared via thermolysis of a carbene-stabilized azidoborane. The reactivity of the fundamentally important HBNH unit (inorganic alkyne analogue) was explored in detail, including attempts to convert this species and related hydrido(azido)borane cations into molecular complexes of BN. This work provides added impetus for the development of molecular precursors that can release bulk boron nitride (a desirable insulator and thermal conductor) under mild conditions, and from solution.
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