期刊
CHEMICAL SCIENCE
卷 8, 期 10, 页码 7132-7137出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7sc03130k
关键词
-
资金
- Welch Foundation [E-1744]
- NSF [CHE-1352439]
- CBIP (UH)
- Studying Abroad Scholarship of Taiwan
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [1352439] Funding Source: National Science Foundation
An unusual transition metal-free cascade reaction of alkynyl carbonazidates was discovered to form azasilacyclopentenes. Mild thermolysis afforded the products via a series of cyclizations, rearrangements, and an alpha-silyl C-H bond insertion (rather than the more common Wolff rearrangement, 1,2-shift, or beta-silyl C-H insertion) to form silacyclopropanes. A mechanistic proposal for the sequence was informed by control experiments and the characterization of reaction intermediates. The substrate scope and post-cascade transformations were also explored.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据