Enantioselective propargylic [1,3]-rearrangements: copper-catalyzed O-to-N migrations toward C–N bond formation

Recent Advances in Catalytic Transformations Involving Copper Acetylides

(2017) Christopher Cordier et al.   SYNTHESIS-STUTTGART

Enantioselective Copper-Catalyzed Propargylic Etherification of Propargylic Esters with Phenols Promoted by Inorganic Base Additives

(2016) Long Shao et al.   ADVANCED SYNTHESIS & CATALYSIS

Variable Time Normalization Analysis: General Graphical Elucidation of Reaction Orders from Concentration Profiles

(2016) Jordi Burés   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Simple Graphical Method to Determine the Order in Catalyst

(2016) Jordi Burés   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Stereospecific Synthesis of α-Amino Allylsilane Derivatives through a [3,3]-Allyl Cyanate Rearrangement. Mild Formation of Functionalized Disiloxanes

(2016) Sylvain Henrion et al.   JOURNAL OF ORGANIC CHEMISTRY

The Synthesis of 5-Amino-dihydrobenzo[b]oxepines and 5-Amino-dihydrobenzo[b]azepines via Ichikawa Rearrangement and Ring-Closing Metathesis

(2016) Monika Chwastek et al.   JOURNAL OF ORGANIC CHEMISTRY

Catalytic Asymmetric [4 + 1] Annulation of Sulfur Ylides with Copper–Allenylidene Intermediates

(2016) Qiang Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Chiral Ferrocenyl P,N-Ligands for Palladium-Catalyzed Asymmetric Formal [3 + 2] Cycloaddition of Propargylic Esters with β-Ketoesters: Access to Functionalized Chiral 2,3-Dihydrofurans

(2016) Yong Zhou et al.   ORGANIC LETTERS

Total Synthesis of K777: Successful Application of Transition-Metal-Catalyzed Alkyne Hydrothiolation toward the Modular Synthesis of a Potent Cysteine Protease Inhibitor

(2016) Erica R. Kiemele et al.   ORGANIC LETTERS

Enantioselective Copper-Catalyzed Formal [4 + 2] Cycloaddition of o-Aminophenol Derivatives with Propargylic Esters for Synthesis of Optically Active 3,4-Dihydro-2H-1,4-benzoxazines

(2016) Zhen-Ting Liu et al.   ORGANIC LETTERS

Highly diastereo-/enantioselective Cu-catalyzed propargylic alkylations of propargyl acetates with cyclic enamines

(2016) Cheng Zhang et al.   RSC Advances

Copper-Catalyzed Intermolecular Asymmetric Propargylic Dearomatization of Indoles

(2015) Wen Shao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Nucleophilic Fluorination of Secondary and Tertiary Propargylic Electrophiles with a Copper-N-Heterocyclic Carbene Complex

(2015) Li-Jie Cheng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed Enantioselective Propargylic Etherification of Propargylic Esters with Alcohols

(2015) Kazunari Nakajima et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mild and Regioselective N-Alkylation of 2-Pyridones in Water

(2015) Xin Hao et al.   ORGANIC LETTERS

Preparation of 3-benzyloxy-2-pyridinone functional linkers: tools for the synthesis of 3,2-hydroxypyridinone (HOPO) and HOPO/hydroxamic acid chelators

(2015) Sarah Gibson et al.   TETRAHEDRON

Recent advances in copper-catalyzed propargylic substitution

(2015) De-Yang Zhang et al.   TETRAHEDRON LETTERS

Rhodium-Catalyzed Chemo-, Regio-, and Enantioselective Addition of 2-Pyridones to Terminal Allenes

(2014) Changkun Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Emerging Applications of Phase-Change Materials (PCMs): Teaching an Old Dog New Tricks

(2014) Dong Choon Hyun et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Highly Regio- and Enantioselective Synthesis of N-Substituted 2-Pyridones: Iridium-Catalyzed Intermolecular Asymmetric Allylic Amination

(2014) Xiao Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Synthesis of Highly Functionalized Dihydrofurans through Copper-Catalyzed Asymmetric Formal [3+2] Cycloaddition of β-Ketoesters with Propargylic Esters

(2014) Fu-Lin Zhu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Copper-Catalyzed Decarboxylative Propargylic Alkylation of Propargyl β-Ketoesters with a Chiral Ketimine P,N,N-Ligand

(2013) Fu-Lin Zhu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ir(I)-Catalyzed Synthesis of N-Substituted Pyridones from 2-Alkoxypyridines via C–O Bond Cleavage

(2013) Shiguang Pan et al.   ORGANIC LETTERS

Direct Evidence of a Dinuclear Copper Intermediate in Cu(I)-Catalyzed Azide-Alkyne Cycloadditions

(2013) B. T. Worrell et al.   SCIENCE

Chiral Tridentate P,N,N Ligands for Highly Enantioselective Copper-Catalyzed Propargylic Amination with both Primary and Secondary Amines as Nucleophiles

(2012) Cheng Zhang et al.   ADVANCED SYNTHESIS & CATALYSIS

Preparation of N-Alkyl 2-Pyridones via a Lithium Iodide Promoted O- to N-Alkyl Migration: Scope and Mechanism

(2012) Sarah Z. Tasker et al.   JOURNAL OF ORGANIC CHEMISTRY

Highly Diastereo- and Enantioselective Cu-Catalyzed [3 + 3] Cycloaddition of Propargyl Esters with Cyclic Enamines toward Chiral Bicyclo[n.3.1] Frameworks

(2012) Cheng Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Transition-Metal-Catalyzed Enantioselective Propargylic Substitution Reactions of Propargylic Alcohol Derivatives with Nucleophiles

(2012) Yoshiaki Nishibayashi   SYNTHESIS-STUTTGART

Synthesis of a New Class of β-IodoN-Alkenyl 2-Pyridones

(2011) Sarah Z. Tasker et al.   ORGANIC LETTERS

Copper-Catalyzed Enantioselective Propargylic Amination of Nonaromatic Propargylic Esters with Amines

(2011) Akiko Yoshida et al.   ORGANIC LETTERS

Copper-Catalyzed Enantioselective Propargylic Amination of Propargylic Esters with Amines: Copper−Allenylidene Complexes as Key Intermediates

(2010) Gaku Hattori et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ru-catalyzed activation of sp3C–O bonds: O- to N-alkyl migratory rearrangement in pyridines and related heterocycles

(2010) Charles S. Yeung et al.   Chemical Science

Catalytic Propargylic Substitution Reactions

(2009) Yoshihiro Miyake et al.   ChemCatChem

Enantioselective Palladium(II)-Catalyzed Formal [3,3]-Sigmatropic Rearrangement of 2-Allyloxypyridines and Related Heterocycles†

(2009) Alessandro Rodrigues et al.   ORGANIC LETTERS

Enantioselective Copper-Catalyzed Propargylic Amination

(2008) Remko J. Detz et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed Asymmetric Propargylic Substitution Reactions of Propargylic Acetates with Amines

(2008) Gaku Hattori et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of SubstitutedN-Benzyl Pyridones via anO- toN-Alkyl Migration

(2008) Erica L. Lanni et al.   JOURNAL OF ORGANIC CHEMISTRY

Asymmetric Organocatalysed [1,3]-Sigmatropic Rearrangements

(2007) Sara Kobbelgaard et al.   CHEMISTRY-A EUROPEAN JOURNAL

Molecular rearrangements through thermal [1,3] carbon shifts

(2007) John E. Baldwin et al.   ORGANIC & BIOMOLECULAR CHEMISTRY