期刊
TETRAHEDRON LETTERS
卷 58, 期 23, 页码 2206-2208出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2017.04.060
关键词
Visible light; Photocatalysis; Thiol-ene reaction; Benzophenone; Anti-Markovnikov addition; Regioselective reaction
资金
- UGC, New Delhi
We report herein a simple, metal- and oxidant-free visible light promoted strategy for an antiMarkovnikov hydrothiolation of unactivated olefins using benzophenone as an inexpensive photocatalyst at room temperature. Anti-Markovnikov adducts of a wide variety of olefins and thiols are formed in highly regioselective manner and good to excellent yields. The present radical thiol-ene reaction is operationally simple and well tolerates a variety of functional groups. (C) 2017 Elsevier Ltd. All rights reserved.
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