期刊
TETRAHEDRON
卷 73, 期 7, 页码 888-899出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2016.12.074
关键词
Trigolute B; Tsuji-Trost allyation; 3-epi-trigolute B; Iridium; Palladium; Dihydroxylation/ lactonization
资金
- CSIR (India) [CSC0108]
A concise approach comprising a combination of the Pd- or Ir-catalyzed Tsuji-Trost allylation and olefin dihydroxylation/acid catalyzed lactonization has been developed to construct the central spirolactone core of trigolutes with the requisite functional groups. A large number of analogues of trigolute B have been synthesized. Furthermore, the synthesis of both (+/-)-trigolute B and (+/-)-3-epi-trigolute B has been accomplished in 4-5 steps from easily accessible building blocks. (C) 2016 Elsevier Ltd. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据