期刊
TETRAHEDRON
卷 73, 期 11, 页码 1511-1516出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2017.01.067
关键词
Reduction; Carbonyl compounds; Alcohols; CpRu(II) complexes; Silanes
资金
- Fundacao para a Ciencia e a Tecnologia [PTDC/QUI-QUI/110080/2009]
- FCT [SFRH/BD/74280/2010, IF/00849/2012]
- [UID/QUI/00100/2013]
- Fundação para a Ciência e a Tecnologia [PTDC/QUI-QUI/110080/2009, SFRH/BD/74280/2010] Funding Source: FCT
This work reports the reduction of a large variety of aldehydes and ketones with the system PhSiH3/[CpRu(PPh3)(2)Cl] in good to excellent yields and high chemoselectivity. The catalyst [CpRu(PPh3)(2)Cl] can be used in at least 12 catalytic cycles with excellent catalytic activity and several substrates were reduced under solvent free conditions. (C) 2017 Elsevier Ltd. All rights reserved.
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