期刊
SYNLETT
卷 28, 期 14, 页码 1680-1694出版社
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0036-1588455
关键词
cross-coupling; iodine; heteroatom; metal-free; aromatic compound
资金
- Japan Society for the Promotion of Science (JSPS)
- Ministry of Education, Culture, Sports, Science and Technology (MEXT)
- Ritsumeikan Global Innovation Research Organization (R-GIRO) project
- JSPS, Challenging Exploratory Research (JSPS)
- JSPS
- Grants-in-Aid for Scientific Research [17K08230] Funding Source: KAKEN
The biaryl unit containing a heteroatom is a key structure in a large number of natural products and -conjugated organic systems. The cross-couplings can provide powerful methods for the construction of biaryls and heterobiaryls; thus the development of a new coupling method has been intensively studied by synthetic chemists. Therefore, the oxidative biaryl coupling reaction of arenes containing a heteroatom is a significantly attractive, convenient, and straightforward route to the synthesis of biaryls due to its operational simplicity avoiding the preparation of the corresponding halogenated and metallated arenes. In this report, recent progress in the field of metal-free oxidative cross-coupling reactions of aromatic compounds using hypervalent iodine(III) reagents, is presented.
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