期刊
SURFACE SCIENCE REPORTS
卷 72, 期 4, 页码 316-349出版社
ELSEVIER
DOI: 10.1016/j.surfrep.2017.06.001
关键词
Two-dimensional molecular network; Self-assembly; Intermolecular forces; Semiconductor surfaces; Scanning tunneling microscopy; Multiscale modelling
资金
- French National Agency [ANR-11-EQPX-0015, ANR-15-CE09-0017, ANR-15-CE29-0005]
- RENATECH network
- CINES Centre
- IDRIS French Supercomputing Centre [c2015/077225, x2016/077225, x2012/096936]
- Agence Nationale de la Recherche (ANR) [ANR-15-CE29-0005, ANR-11-EQPX-0015, ANR-15-CE09-0017] Funding Source: Agence Nationale de la Recherche (ANR)
Understanding the physical and chemical processes in which local interactions lead to ordered structures is of particular relevance to the realization of supramolecular architectures on surfaces. While spectacular patterns have been demonstrated on metal surfaces, there have been fewer studies of the spontaneous organization of supramolecular networks on semiconductor surfaces, where the formation of covalent bonds between organics and adatoms usually hamper the diffusion of molecules and their subsequent interactions with each other. However, the saturation of the dangling bonds at a semiconductor surface is known to make them inert and offers a unique way for the engineering of molecular patterns on these surfaces. This review describes the physicochemical properties of the passivated B-Si(111)-(root 3x root 3) R30 degrees surface, that enable the self-assembly of molecules into a rich variety of extended and regular structures on silicon. Particular attention is given to computational methods based on multi-scale simulations that allows to rationalize the relative contribution of the dispersion forces involved in the self-assembled networks observed with scanning tunneling microscopy. A summary of state of the art studies, where a fine tuning of the molecular network topology has been achieved, sheds light on new frontiers for exploiting the construction of supramolecular structures on semiconductor surfaces. (C) 2017 Elsevier B.V. All rights reserved.
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