期刊
SENSORS AND ACTUATORS A-PHYSICAL
卷 258, 期 -, 页码 201-207出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.sna.2017.03.008
关键词
Bismuth sodium titanate; Lead-free; Mechanical properties; Incipient piezoceramics; Phase transition; Piezoelectric properties
资金
- R&D program for the strategic core materials - Ministry of Trade, Industry and Energy, Republic of Korea
Lead-free (1-x)(Bi1/2Na1/2)TiO3-xSrTiO(3) (BNST, 0 <= x <= 0.25) ceramics were prepared by a conventional solid-state reaction. The effect of increasing the concentration of SrTiO3 (ST) on the phase transition behavior was investigated using x-ray diffraction patterns, field-induced polarization, and strain curves. As the ST concentrations increased, a ferroelectric to ergodic relaxor phase transition occurred. At x=0.25, the highest strain was observed despite the piezoelectric charge constant being the lowest, and the ferroelectric and ergodic relaxor phases seemed to coexist. In order to investigate the mechanical properties of BNST ceramics, the resonance and antiresonance frequencies of various vibration modes were obtained, and the various tensors of elastic compliances were subsequently calculated. Because the resonance and antiresonance frequencies of the ergodic relaxor piezoceramics cannot be easily identified due to the absence of a remanent polarization and strain after the removal of the electric field, some tensors of elastic compliance of BNST with x=0.25 were obtained by extrapolation of the compliance variation as a function of ST concentrations. (C) 2017 Elsevier B.V. All rights reserved.
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