期刊
RUSSIAN JOURNAL OF ORGANIC CHEMISTRY
卷 53, 期 5, 页码 679-685出版社
MAIK NAUKA/INTERPERIODICA/SPRINGER
DOI: 10.1134/S1070428017050062
关键词
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Substitution of the nitro group for methyl in the position 4 of the picrylic fragment of 1-(2,4,6-trinitrophenyl)-2,2-diphenylhydrazyl increases the relative stability of hydrazyl radical in reaction with CH-acids. The reaction rate of 1-(2,4,6-trinitrophenyl)-2,2-diphenylhydrazyl with acetylacetone and ethyl acetoacetate is described with equations of first order with respect to the radical and the CH-acid and is determined by the energy of electron transfer from HOMO of CH-acid on LUMO of the radical, which is its acceptor.
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