Article
Environmental Sciences
Yuhang Li, Hui Cao, Wenli Liu, Pengtao Liu
Summary: In this study, a PVA/CNF/Fe3O4 hybrid hydrogel was prepared using the in-situ co-precipitation method. The hybrid hydrogel showed high efficiency in catalytic degradation of tetracycline.
Article
Chemistry, Physical
Jingmai Li, Shangying Li, Zhou Cao, Yunpu Zhao, Qizhao Wang, Hongfei Cheng
Summary: In this study, a CoFe2O4/kaolinite (CFO/K) composite photocatalyst was successfully synthesized, and tetracycline hydrochloride (TCH) was degraded through synergetic photo-Fenton reaction. Compared with pure CoFe2O4, CFO/K-40% exhibited higher photocatalytic degradation efficiency due to its larger specific surface area, abundant surface active sites, and higher photogenic electron hole pairs separation efficiency.
APPLIED CLAY SCIENCE
(2023)
Article
Engineering, Chemical
Hongfei Yin, Ying Cao, Tianle Fan, Pengfei Li, Shen-ming Chen, Xiaoheng Liu
Summary: Effective heterogeneous catalysts for the removal of refractory organic pollutants are highly desirable. In this study, FeOOH/BOBC-2 hybrids were found to exhibit superior performance as photo-Fenton catalysts for tetracycline hydrochloride degradation. Factors such as catalyst dosage, TCH concentration, H2O2 amount, and initial pH were investigated and found to significantly affect the performance of the catalyst. Enhanced specific surface areas and effective charge separation were key contributors to the improved photo-Fenton performance.
JOURNAL OF THE TAIWAN INSTITUTE OF CHEMICAL ENGINEERS
(2021)
Article
Engineering, Environmental
Wenjuan He, Hongping Jia, Zuopeng Li, Chang-qing Miao, Runhua Lu, Sanbing Zhang, Zhiqiang Zhang
Summary: In this study, a novel catalyst was prepared to enhance the efficiency of photocatalytic degradation of ciprofloxacin. The results showed that the catalyst exhibited excellent photo-Fenton catalytic activity and good reusability.
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
(2022)
Article
Environmental Sciences
Kang-Ping Cui, Ting-Ting Yang, Yi-Han Chen, Rohan Weerasooriya, Guang-Hong Li, Kai Zhou, Xing Chen
Summary: The study successfully prepared recyclable magnetic Fe3O4/g-C3N4 through electrostatic self-assembly method, and developed a heterogeneous optical Fenton system for tetracycline removal. With a removal efficiency of 99.8% under certain conditions, the Fe3O4/g-C3N4 photocatalyst can be recycled five times with minimal efficiency loss.
ENVIRONMENTAL TECHNOLOGY
(2022)
Article
Chemistry, Physical
Xiaoqiang Shi, Lina Wang, Achuo Anitta Zuh, Yuefa Jia, Fei Ding, Hongfei Cheng, Qizhao Wang
Summary: The FeWO4/BiOCl composite was successfully prepared and demonstrated significantly enhanced photocatalytic performance in the photo-Fenton degradation of tetracycline hydrochloride. The optimized reaction conditions were identified, and the excellent recyclability of the composite was shown. The enhanced performance was attributed to effective charge separation and the production of more center dot OH radicals.
JOURNAL OF ALLOYS AND COMPOUNDS
(2022)
Article
Chemistry, Physical
Tingting Zhang, Xing Liu, Yanqiu Jiang, Xiaowei Zheng, Jian Zhang, Yudong Li, Defeng Li, Kaifeng Lin
Summary: Fe2O3-on-ZrO2 polypods were synthesized through metal organic frameworks (MOFs) derivation strategy. Under UV-vis light irradiation, Fe2O3-on-ZrO2 efficiently degraded TC-HCl and accelerated the iron cycle. This study demonstrated a new structure and degradation mechanism, which will promote the rational regulation of materials with special morphology and structure.
APPLIED SURFACE SCIENCE
(2023)
Article
Chemistry, Physical
Zhou Cao, Yuefa Jia, Qizhao Wang, Hongfei Cheng
Summary: A Fe/graphitic carbon nitride/kaolinite composite photocatalyst was successfully prepared for the first time and showed high degradation efficiency for TCH in the photo-Fenton system. Free radical scavenging experiments confirmed that hydroxyl radicals were the main active substances. The enhanced photocatalytic activity of the composite can be attributed to the large specific surface area of kaolinite and Fe acting as a photo-generated electron acceptor.
APPLIED CLAY SCIENCE
(2021)
Article
Chemistry, Physical
Tong Zhang, Xiaojun Guo, Hebing Pei, Fei Zha, Xiaohua Tang, Haifeng Tian, Ruibin Guo, Nijuan Liu, Zunli Mo
Summary: In this study, α-Fe2O3/MIL-53(Fe) composite was successfully prepared and used as a photo-Fenton catalyst for the degradation of TC-HCl. The composite exhibited excellent performance in TC-HCl degradation due to the synergistic effect between MIL-53(Fe) and α-Fe2O3. The heterojunction structure formed in the composite played a crucial role in reducing the band gap, enhancing visible light absorption, and improving the separation and transportation of photo-induced carriers.
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
(2023)
Article
Engineering, Environmental
Xiao Zhang, Bin Ren, Xi Li, Biming Liu, Shiwen Wang, Peng Yu, Yanhua Xu, Guoqiang Jiang
Summary: The carbon-bridge-modified malonamide/g-C3N4/Fe3O4 catalyst was prepared for efficient removal of tetracycline in water, showing good performance and environmental friendliness.
JOURNAL OF HAZARDOUS MATERIALS
(2021)
Article
Environmental Sciences
Shuai Mao, Chun Liu, Yi Wu, Mingzhu Xia, Fengyun Wang
Summary: This study fabricated an efficient P and Fe co-doping graphitic carbon nitride catalyst, which exhibited better performance in the degradation of tetracycline hydrochloride. The introduction of 2-hydroxyphosphonoacetic acid increased the specific surface area of the catalyst and improved charge separation and transfer efficiency.
Article
Chemistry, Physical
Zhou Cao, Yunpu Zhao, Zhaohui Zhou, Qizhao Wang, Qiong Mei, Hongfei Cheng
Summary: A heterogeneous photo-Fenton catalyst, LaFeO3/BiOI, with enhanced degradation activity for TCH was developed. The catalyst exhibited high degradation efficiency and stability, suggesting promising prospects for the removal of antibiotic pollutants. The study also proposed new insights into the degradation mechanisms of TCH in the heterojunction system.
APPLIED SURFACE SCIENCE
(2022)
Article
Materials Science, Multidisciplinary
Rupali Chavan, Nilesh Bhat, Santosh Parit, Kitchamsetti Narasimharao, Rupesh S. Devan, Rahul B. Patil, Vijay C. Karade, Nilesh Pawar, Jin Hyeok Kim, Jyoti P. Jadhav, Ashok D. Chougale
Summary: This work presents a facile green synthesis method for producing Fe3O4 magnetic nanoparticles (MNPs), which exhibit high catalytic activity in Fenton and photo-Fenton reduction reactions. The MNPs show spherical morphology and have an average diameter of 6.3 +/- 1.1 nm. The study demonstrates the superior efficiency of the MNPs in both processes at varied pH ranges. Additionally, the MNPs exhibit good reusability and can effectively reduce dye and Cr(VI) loads in water treatment processes.
MATERIALS CHEMISTRY AND PHYSICS
(2023)
Article
Chemistry, Physical
Zihao Cui, Peng Wang, Xiaolei Liu, Xizhuang Liang, Qianqian Zhang, Zeyan Wang, Zhaoke Zheng, Hefeng Cheng, Yuanyuan Liu, Ying Dai, Baibiao Huang
Summary: This study synthesized BiVO4@CuOx composite catalyst for efficient degradation of tetracycline through Fenton reaction assisted by light irradiation. Factors influencing degradation were investigated, and a new suggestion for designing photo assisted Fenton-like catalyst was proposed.
SURFACES AND INTERFACES
(2021)
Article
Chemistry, Physical
Chuanqi Cao, Zuyi Lu, Linxing Wang, Ling Li, Dongzhu Deng, Danling Liao, Chuangrong Mo
Summary: Ce-doped BiFeO3 precursors were synthesized and Ce-doped BiFeO3 (BCFO) was obtained through high-temperature calcination. Ce doping reduced the band gap of BiFeO3 and enhanced the photocatalytic performance. The photocurrent density, impedance, and saturation magnetization of BCFO increased significantly. BCFO-7 (7% Ce doping) showed excellent catalytic activity in the degradation of tetracycline, with a high detoxification effect and stable photocatalytic process.
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY
(2024)