4.5 Article

Photo-fenton refreshable Fe3O4@HCS adsorbent for the elimination of tetracycline hydrochloride

期刊

RESEARCH ON CHEMICAL INTERMEDIATES
卷 44, 期 1, 页码 1-11

出版社

SPRINGER
DOI: 10.1007/s11164-017-3028-y

关键词

Tetracycline hydrochloride; Recyclable Fe3O4@HCS; Adsorption; Photo-Fenton degradation

资金

  1. National Natural Science Foundation of China [21673073, 21677048, U1407102, 21377038]
  2. National Basic Research Program of China (973 Program) [2013CB632403]
  3. Science and Technology Commission of Shanghai Municipality [14230710500, 14ZR1440500, 16JC1401400]
  4. PetroChina Innovation Foundation [2015D-5006-0402]
  5. Fundamental Research Funds for the Central Universities [222201717003]

向作者/读者索取更多资源

A yolk-shell-structured sphere composed of a superparamagnetic Fe3O4 core and a carbon shell (Fe3O4@HCS) was etched from Fe3O4@SiO2@carbon by NaOH, which was synthesized through the layer-by-layer coating of Fe3O4. This yolk-shell composite has a shell thickness of ca. 27 nm and a high specific surface area of 213.2 m(2) g(-1). Its performance for the magnetic removal of tetracycline hydrochloride from water was systematically examined. A high equilibrium adsorption capacity of ca. 49.0 mg g(-1) was determined. Moreover, the adsorbent can be regenerated within 10 min through a photo-Fenton reaction. A stable adsorption capacity of 44.3 mg g(-1) with a fluctuation < 10% is preserved after 5 consecutive adsorption-degradation cycles, demonstrating its promising application potential in the decontamination of sewage water polluted by antibiotics.

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