4.8 Article

Long-wavelength fluctuations and the glass transition in two dimensions and three dimensions

出版社

NATL ACAD SCIENCES
DOI: 10.1073/pnas.1607226113

关键词

colloidal glass transition; dimensionality; long-wavelength fluctuations; phase transition; two-dimensional physics

资金

  1. National Science Foundation [CMMI-1250235, DMR-1105417]
  2. National Aeronautics and Space Administration Grant [NNX 13AR67G]
  3. National Science Foundation Materials Research Science and Engineering Center Program [DMR-1420073]
  4. Division Of Materials Research
  5. Direct For Mathematical & Physical Scien [1105417] Funding Source: National Science Foundation

向作者/读者索取更多资源

Phase transitions significantly differ between 2D and 3D systems, but the influence of dimensionality on the glass transition is unresolved. We use microscopy to study colloidal systems as they approach their glass transitions at high concentrations and find differences between two dimensions and three dimensions. We find that, in two dimensions, particles can undergo large displacements without changing their position relative to their neighbors, in contrast with three dimensions. This is related to Mermin-Wagner long-wavelength fluctuations that influence phase transitions in two dimensions. However, when measuring particle motion only relative to their neighbors, two dimensions and three dimensions have similar behavior as the glass transition is approached, showing that the long-wavelength fluctuations do not cause a fundamental distinction between 2D and 3D glass transitions.

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