4.7 Article

Temperature-dependent R-curve behavior of the lead-free ferroelectric 0.615Ba(Zr0.2Ti0.8)O-3-0.385(Ba0.7Ca0.3)TiO3 ceramic

期刊

ENGINEERING FRACTURE MECHANICS
卷 144, 期 -, 页码 68-77

出版社

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.engfracmech.2015.06.069

关键词

Fracture mechanics; Crack growth; R-curve; BZT-BCT; Ferroelasticity

资金

  1. Deutsche Forschungsgemeinschaft [Sonderforschungsbereich 595, WE4972/2-1]
  2. AdRIA Hesse state center for Adaptronics

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The temperature-dependent crack growth resistance behavior of the lead-free (1-x)Ba(Zr0.2Ti0.8)O-3-x(Ba0.7Ca0.3)TiO3 (x = 0.385) ceramic was characterized using compact-tension specimens from 25 degrees C to 60 degrees C. The observed plateau fracture toughness at 25 degrees C was found to be approximately 37% lower than commercial Pb(Zr,Ti)O-3. At elevated temperature, the maximum fracture toughness displayed a decrease, which was found to be related to the temperature-dependent elastic and ferroelastic properties. Mechanical measurements are presented that demonstrate decreasing effective switching strain, coercive stress and Young's modulus with increasing temperature. (C) 2015 Elsevier Ltd. All rights reserved.

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