期刊
ORGANIC LETTERS
卷 19, 期 14, 页码 3831-3834出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.7b01705
关键词
-
资金
- NSFC [21232004, 21472071, 21602087]
- PAPD of Jiangsu Higher Education Institutions
- Outstanding Youth Fund of JSNU [YQ2015003]
- NSF of Jiangsu Province [BK20151163, BK20160212]
- Qing Lan Project
- NSF of Jiangsu Education Committee [15KJB150006]
A new Ag/Bronsted acid to-catalyzed spiroketalization of beta-alkynyl ketones with parq-quincine methides (p-QMs) has been: established, enabling multiple C-C and C-O bond-forming events to access densely functionalized spiro[chrcimane-2,1'-isochromene]. derivatives with generally excellent diastereoselectivity and good yields. A reasonable mechanism for forming these 6,6-dibenzannulated spiraetals involving. 6-endo-dig oxo-cyclization and 1,6-addition-cyclization cascades is proposed.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据