期刊
ORGANIC LETTERS
卷 19, 期 11, 页码 2989-2992出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.7b01222
关键词
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资金
- Boston University and National Science Foundation [ABB CHE-1555300]
- NSF [CHE-0619339, CHE0443618]
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [1555300] Funding Source: National Science Foundation
We report the exploration into photoredox generation of carbonyl ylides from benzylic epoxides using newly designed 4-mesityl-2,6-diphenylpyrylium tetrafluoroborate (MDPT) and 4-mesityl-2,6-di-p-tolylpyrylium tetrafluoroborate (MD(p-tolyl)PT) catalysts. These catalysts are excited at visible wavelengths, are highly robust, and exhibit some of the highest oxidation potentials reported. Their utility was demonstrated in the mild and efficient generation of carbonyl ylides from benzylic epoxides that otherwise could not be carried out by current common photoredox catalysts.
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