期刊
ORGANIC LETTERS
卷 19, 期 5, 页码 1248-1251出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.7b00458
关键词
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资金
- National Research Foundation of Korea (NRF) grant - Korean government [2014R1A5A1011165, 2007-0093864]
- BK21 Plus fellowship
A highly regioselective rhodium-catalyzed intermolecular carbonylative [2 + 2 + 1] cycloaddition of alkynes using alcohol as a CO surrogate to access 4-methylene-2-cydopenten-l-ones has been developed. In this transformation, the alcohol performs multiple roles, including generating the Rh-H intermediate, functioning as the CO source, and assisting in the isomerization of the alkyne. Alkynes can act as both the olefin and the alkyne partner in the cyclopentenone core.
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