期刊
ORGANIC LETTERS
卷 19, 期 8, 页码 2186-2189出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.7b00904
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资金
- DST, New Delhi [IFA 14, CH-157, GAP-0520]
- CSIR
Cp*CO(III)-catalyzed C-H functionalization cascade of N-methoxyamides, with alkynedione has been reported for the synthesis of indolizidine scaffolds under redox-neutral conditions. The reaction displays broad functional group tolerance along with excellent yield. The reaction proceeds with kinetically relevant C-H bond activation through carboxylate assistance with excellent diastereoselectivity and complete opposite selectivity with respect to alkyne insertion.
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