期刊
ORGANIC LETTERS
卷 19, 期 24, 页码 6674-6677出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.7b03398
关键词
-
资金
- CAS Interdisciplinary Innovation Team
- National Natural Science Foundation of China [21672199]
A new, facile, and efficient protocol for the synthesis of polysubstituted conjugated 1,3-dienes through Ni-catalyzed tandem dimerization/cross-coupling reaction of diarylacetylenes and arylboronic acids in the presence of a catalytic amount of B(2)pin(2) has been developed. A series of arynes and arylboronic acids with different substituents participated well in this catalytic system, affording a variety of useful conjugated 1,3-dienes.
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