期刊
ORGANIC LETTERS
卷 19, 期 19, 页码 5244-5247出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.7b02522
关键词
-
资金
- FWO (PhD Fellowship of the Research Foundation - Flanders)
- KU Leuven [OT/14/067]
- Hercules Foundation [AKUL1311]
- European Union's Horizon research and innovation program under the Marie Sklodowska-Curie grant [721290]
A convenient transformation of phenols into the corresponding aryl fluorosulfates is presented: the first protocol to completely circumvent direct handling of gaseous sulfuryl fluoride (SO2F2). The proposed method employs 1,1'-sulfonyldiimidazole as a precursor to generate near-stoichiometric amounts of SO2F2 gas using a two-chamber reactor. With NMR studies, it was shown that this ex situ gas evolution is extremely rapid, and a variety of phenols and hydroxylated heteroarenes were fluorosulfated in good to excellent yields.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据