期刊
ORGANIC LETTERS
卷 19, 期 7, 页码 1734-1737出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.7b00503
关键词
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资金
- NSFC [21672169]
- 1000 Youth Talents Plan
- Education Department of Shaanxi Province [12JS113]
An efficient method for the construction of dibenzo [b,d]azepines containing two distinct stereogenic elements in a highly diastereoselective fashion is described. The key of the [5 + 2] reaction is to form a pi-allylialladitin species through sequential C-H activation and regiospecific migratory insertion of the diene.This observation contrasts with the behavior of 1,2-alkenes that generally underwent direct alkenylation via beta-hydride elimination.
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