期刊
NEW JOURNAL OF CHEMISTRY
卷 41, 期 18, 页码 9857-9865出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7nj00442g
关键词
-
资金
- National Natural Science Foundation of China [21603054]
- Natural Science Foundation of Hebei Province [B2015204003, B2016204131]
- Young Top-notch Talents Foundation of Hebei Provincial Universities [BJ2016027]
- Natural Science Foundation of Agricultural University of Hebei [ZD201506, ZD201613]
Bimetallic AgPd nanoparticles anchored on metal-organic framework (UiO-66) derived N-doped porous carbon (NPC-UiO-66) was fabricated and used as a catalyst for the catalytic transfer hydrogenation of nitroarenes using formic acid-formate as the hydrogen source. The results demonstrated that the Ag1Pd9@ NPC-UiO-66 composite exhibited extraordinary catalytic activity toward the hydrogenation of nitroarenes to anilines at room temperature. A series of substituted nitroarenes were successfully converted to the corresponding anilines in high yields under ambient conditions with other reducible groups remaining intact. The superior catalytic performance of the prepared catalyst can be attributed to the synergistic effect between the highly dispersed AgPd nanoparticles and the unique structure of the NPC-UiO-66 support, as well as the high adsorption ability of the catalyst for the nitroarenes.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据