Phosphovanadomolybdic acid catalyzed direct C–H trifluoromethylation of (hetero)arenes using NaSO2CF3 as the CF3 source and O2 as the terminal oxidant

Palladium-Catalyzed Trifluoromethylation of (Hetero)Arenes with CF3 Br

(2016) Kishore Natte et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Photoorganocatalysed and visible light photoredox catalysed trifluoromethylation of olefins and (hetero)aromatics in batch and continuous flow

(2016) Quentin Lefebvre et al.   CHEMICAL COMMUNICATIONS

Catalyst-free direct C–H trifluoromethylation of arenes in water–acetonitrile

(2016) Dangui Wang et al.   GREEN CHEMISTRY

Simple and Clean Photoinduced Aromatic Trifluoromethylation Reaction

(2016) Lu Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Phosphovanadomolybdic acid catalyzed desulfurization–oxygenation of secondary and tertiary thioamides into amides using molecular oxygen as the terminal oxidant

(2016) Ning Xu et al.   NEW JOURNAL OF CHEMISTRY

Redox-ligand sustains controlled generation of CF3 radicals by well-defined copper complex

(2016) Jérémy Jacquet et al.   Chemical Science

Heterogeneous Platinum-Catalyzed CH Perfluoroalkylation of Arenes and Heteroarenes

(2015) Lin He et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Condensed-Phase, Halogen-Bonded CF3I and C2F5I Adducts for Perfluoroalkylation Reactions

(2015) Filippo Sladojevich et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Introducing a new radical trifluoromethylation reagent

(2015) Azusa Sato et al.   CHEMICAL COMMUNICATIONS

Regioselective direct oxidative C–H cyanation of quinoline and its derivatives catalyzed by vanadium-containing heteropoly acids

(2015) Kazuya Yamaguchi et al.   CHEMICAL COMMUNICATIONS

Carbon Trifluoromethylation Reactions of Hydrocarbon Derivatives and Heteroarenes

(2015) Concepción Alonso et al.   CHEMICAL REVIEWS

Recent Advances in Polyoxometalate-Catalyzed Reactions

(2015) Sa-Sa Wang et al.   CHEMICAL REVIEWS

Manganese-Catalyzed Aerobic Oxytrifluoromethylation of Styrene Derivatives Using CF3SO2Na as the Trifluoromethyl Source

(2015) Yi Yang et al.   JOURNAL OF ORGANIC CHEMISTRY

A scalable and operationally simple radical trifluoromethylation

(2015) Joel W. Beatty et al.   Nature Communications

Application of Langlois’ Reagent in Trifluoromethylation Reactions

(2014) Cai Zhang   ADVANCED SYNTHESIS & CATALYSIS

Addition of CF3 across unsaturated moieties: a powerful functionalization tool

(2014) Estíbaliz Merino et al.   CHEMICAL SOCIETY REVIEWS

Graphitic Carbon Nitride Polymer as a Recyclable Photoredox Catalyst for Fluoroalkylation of Arenes

(2014) Moritz Baar et al.   CHEMISTRY-A EUROPEAN JOURNAL

Highly efficient Cu(I)-catalyzed trifluoromethylation of aryl(heteroaryl) enol acetates with CF3 radicals derived from CF3SO2Na and TBHP at room temperature

(2014) Yang Lu et al.   JOURNAL OF FLUORINE CHEMISTRY

Metal-Free Direct CH Perfluoroalkylation of Arenes and Heteroarenes Using a Photoredox Organocatalyst

(2013) Lei Cui et al.   ADVANCED SYNTHESIS & CATALYSIS

Direct Trifluoromethylation of the CH Bond

(2013) Hui Liu et al.   ADVANCED SYNTHESIS & CATALYSIS

Silver-Catalyzed Hydrotrifluoromethylation of Unactivated Alkenes with CF3SiMe3

(2013) Xinyue Wu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Silver-catalysed trifluoromethylation of arenes at room temperature

(2013) Sangwon Seo et al.   CHEMICAL COMMUNICATIONS

Transition-metal-free oxidative trifluoromethylation of unsymmetrical biaryls with trifluoromethanesulfinate

(2013) Yu-Dong Yang et al.   CHEMICAL COMMUNICATIONS

Copper-catalyzed trifluoromethylation of N-arylacrylamides “on water” at room temperature

(2013) Fang Yang et al.   CHEMICAL COMMUNICATIONS

Copper-Catalyzed One-Pot Trifluoromethylation/Aryl Migration/Desulfonylation and C(sp2)–N Bond Formation of Conjugated Tosyl Amides

(2013) Wangqing Kong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A “Renaissance” in Radical Trifluoromethylation

(2012) Armido Studer   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Studies on the redox turnover of polyoxometalates using potentiometric chemical sensors

(2012) Alisa Rudnitskaya et al.   NEW JOURNAL OF CHEMISTRY

Rhenium-Catalyzed Trifluoromethylation of Arenes and Heteroarenes by Hypervalent Iodine Reagents

(2012) Esteban Mejía et al.   ACS Catalysis

Aromatic Trifluoromethylation with Metal Complexes

(2011) Olesya A. Tomashenko et al.   CHEMICAL REVIEWS

Catalysis for fluorination and trifluoromethylation

(2011) Takeru Furuya et al.   NATURE

Trifluoromethylation of arenes and heteroarenes by means of photoredox catalysis

(2011) David A. Nagib et al.   NATURE

Palladium-Catalyzed C–H Perfluoroalkylation of Arenes

(2011) Rebecca N. Loy et al.   ORGANIC LETTERS

Innate C-H trifluoromethylation of heterocycles

(2011) Y. Ji et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

Electron Transfer−Oxygen Transfer Oxygenation of Sulfides Catalyzed by the H5PV2Mo10O40Polyoxometalate

(2010) Alexander M. Khenkin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Trifluoromethylation of various aromatic compounds by CF3I in the presence of Fe(II) compound, H2O2 and dimethylsulfoxide

(2009) Tatsuhito Kino et al.   JOURNAL OF FLUORINE CHEMISTRY

Fluorine in medicinal chemistry

(2007) Sophie Purser et al.   CHEMICAL SOCIETY REVIEWS