4.6 Article

Facile preparation of carbon wrapped copper telluride nanowires as high performance anodes for sodium and lithium ion batteries

期刊

NANOTECHNOLOGY
卷 28, 期 14, 页码 -

出版社

IOP PUBLISHING LTD
DOI: 10.1088/1361-6528/aa5b62

关键词

carbon wrapped nanowires; copper telluride; one-dimensional; sodium/lithium ion battery; anode material

资金

  1. National Natural Science Foundation of China [21303047]
  2. Program for One Hundred Person Project of Guangdong University of Technology [220418084]

向作者/读者索取更多资源

Uniform carbon wrapped copper telluride nanowires were successfully prepared by using an in situ conversion reaction. The length of these nanowires is up to several micrometers and the width is around 30-40 nm. The unique one dimensional structure and the presence of conformal carbon coating of copper telluride greatly accommodate the large volumetric changes during cycling, significantly increase the electrical conductivity and reduce charge transfer resistance. The copper telluride nanowires show promising performance in a lithium ion battery with a discharge capacity of 130.2 mA h g(-1) at a high current density of 6.0 A g(-1) (26.74 C) and a stable cycling performance of 673.3 mA h g(-1) during the 60th cycle at 100 mA g(-1). When evaluated as anode material for a sodium ion battery, the copper telluride nanowires deliver a reversible capacity of 68.1 mA h g(-1) at 1.0 A g(-1) (similar to 4.46 C) and have a high capacity retention of 177.5 mA h g(-1) during the 500th cycle at 100 mA g(-1).

作者

我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。

评论

主要评分

4.6
评分不足

次要评分

新颖性
-
重要性
-
科学严谨性
-
评价这篇论文

推荐

Article Materials Science, Multidisciplinary

Iron doping of NiSe2 nanosheets to accelerate reaction kinetics in sodium-ion half/full batteries

Jing Liu, Juan Xie, Huilong Dong, Huaixin Wei, Chencheng Sun, Jun Yang, Hongbo Geng

Summary: Fe-doped NiSe2@C nanosheets with a porous structure exhibit higher capacity, better cycle stability, and higher rate performance in sodium-ion batteries due to the optimized porous structure and improved Na+ mobility.

SCIENCE CHINA-MATERIALS (2023)

Article Chemistry, Multidisciplinary

Reconstruction of Electric Double Layer for Long-Life Aqueous Zinc Metal Batteries

Yang Yang, Haiming Hua, Zeheng Lv, Minghao Zhang, Chaoyue Liu, Zhipeng Wen, Haodong Xie, Weidong He, Jinbao Zhao, Cheng Chao Li

Summary: A SiO2 reinforced-sodium alginate (SA) hybrid film is designed to regulate the solid-liquid interaction energy and spatial distribution of species in the electric double layer (EDL) near the Zn electrode. The reconfigured EDL ensures dendrite-free Zn deposition and eliminates interface parasitic side reactions.

ADVANCED FUNCTIONAL MATERIALS (2023)

Article Chemistry, Multidisciplinary

Dynamically Interfacial pH-Buffering Effect Enabled by N-Methylimidazole Molecules as Spontaneous Proton Pumps toward Highly Reversible Zinc-Metal Anodes

Minghao Zhang, Haiming Hua, Pengpeng Dai, Zheng He, Lianhuan Han, Peiwen Tang, Jin Yang, Pengxiang Lin, Yufei Zhang, Dongping Zhan, Jianken Chen, Yu Qiao, Cheng Chao Li, Jinbao Zhao, Yang Yang

Summary: A dynamically interfacial pH-buffering strategy using N-methylimidazole (NMI) additive is proposed to eliminate the accumulation of by-products by removing detrimental OH- at the zinc/electrolyte interface. An interfacial absorption layer assembled by NMI and protonated NMI (NMIH+) is found to replenish the interface with protons constantly, resulting in excellent cumulative plating capacity and ultrahigh Coulombic efficiency for zinc electrodes. Additionally, the NMI/NMIH+ buffer additive enhances the dissolution/deposition process on the cathode, leading to enhanced cycling capacity.

ADVANCED MATERIALS (2023)

Article Chemistry, Inorganic & Nuclear

Nickel cobalt selenides on black phosphorene with fast electron transport for high-energy density sodium-ion half/full batteries

Jun Yang, Chenrui Zhang, Jitao Geng, Yangyang Sui, Huaixin Wei, Chencheng Sun, Hongbo Geng, Yushen Liu

Summary: In this study, a novel approach of in situ chemical anchoring of nickel cobalt selenide (Ni3Se4/CoSe2) on two-dimensional black phosphorene (BP) was proposed. The resulting BP@Ni3Se4/CoSe2 heterostructure effectively buffers volume expansion and facilitates electron/ion transfer, leading to superior sodium storage performance in half cells.

INORGANIC CHEMISTRY FRONTIERS (2023)

Article Nanoscience & Nanotechnology

Stepwise Multi-Cross-Linking Bioink for 3D Embedded Bioprinting to Promote Full-Thickness Wound Healing

Lili Hao, Xiwang Tao, Miao Feng, Ke Zhou, Yiyan He, Jun Yang, Hongli Mao, Zhongwei Gu

Summary: The emergence and innovation of three-dimensional (3D) bioprinting provide new development opportunities for tissue engineering and regenerative medicine. A stepwise multi-cross-linking strategy using thermosensitive bioinks has been proposed to achieve temperature-controlled 3D embedded bioprinting, allowing for complex structures with excellent shape fidelity and maintenance of cell viability.

ACS APPLIED MATERIALS & INTERFACES (2023)

Article Chemistry, Multidisciplinary

Tailoring Anion Association Strength Through Polycation-Anion Coordination Mechanism in Imidazole Polymeric Ionic Liquid-Based Artificial Interphase toward Durable Zn Metal Anodes

Jiaqi Ke, Zhipeng Wen, Yang Yang, Rong Tang, Yongchao Tang, Minghui Ye, Xiaoqing Liu, Yufei Zhang, Cheng Chao Li

Summary: Artificial interface layer engineering is an effective strategy for protecting zinc anode, but the high conductivity of most layers contributes to parasitic reactions. A new imidazole polymeric ionic liquid layer is designed to inhibit anion diffusion and promote zinc ion migration. The resulting cells demonstrate high bulk ionic conductivity and capacity retention, indicating potential practical application.

ADVANCED FUNCTIONAL MATERIALS (2023)

Article Chemistry, Multidisciplinary

Regulation of Ionic Distribution and Desolvation Activation Energy Enabled by In Situ Zinc Phosphate Protective Layer toward Highly Reversible Zinc Metal Anodes

Shengzhao Zhang, Minghui Ye, Yufei Zhang, Yongchao Tang, Xiaoqing Liu, Cheng Chao Li

Summary: A protective Zn-3(PO4)(2)·4H2O layer is constructed on Zn foil using a hydrothermal method, improving the performance of Zn metal anodes in aqueous Zn metal batteries. The Zn@ZnPO anodes show no dendritic growth and maintain their stability after cycles, enabling highly reversible Zn plating/stripping behavior and long cycling lifespans.

ADVANCED FUNCTIONAL MATERIALS (2023)

Article Chemistry, Multidisciplinary

Hydrated Eutectic Electrolytes Stabilizing Quasi-Underpotential Mg Plating/Stripping for High-Voltage Mg Batteries

Guigui Liu, Yongchao Tang, Hongqing Li, Jiangfeng He, Minghui Ye, Yufei Zhang, Zhipeng Wen, Xiaoqing Liu, Cheng Chao Li

Summary: Achieving a stable quasi-underpotential magnesium plating/stripping chemistry (UPMC) on a zinc substrate in new hydrated eutectic electrolytes (HEEs) can prevent anode passivation in aqueous rechargeable magnesium batteries (ARMBs). The unique eutectic property of the electrolyte expands the lower limit of the electrochemical stability window (ESW) and allows for reversible UPMC. When combined with sulfonic acid-doped polyaniline (SPANI) cathodes, UPMC-based full cells exhibit high energy/power densities and voltage plateau, surpassing conventional aqueous systems.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2023)

Article Environmental Sciences

Modulating photothermal properties by integration of fined Fe-Co in confined carbon layer of SiO2 nanosphere for pollutant degradation and solar water evaporation

Rongrong Du, Hongyang Zhu, Hongyao Zhao, Hao Lu, Chang Dong, Mengting Liu, Fu Yang, Jun Yang, Jun Wang, Jianming Pan

Summary: Environmental governance using photothermal materials, specifically for the separation of organic pollutants and freshwater regeneration, is gaining attention. A functional nanosphere composed of a silica core coated by a carbon layer encapsulated plasmonic bimetallic FeCo2O4 spinel was constructed. This material exhibits multiple environmental governing functions, such as PMS activation to degrade pollutants and photothermal interfacial solar water evaporation.

ENVIRONMENTAL RESEARCH (2023)

Article Chemistry, Multidisciplinary

Copper Doping of CoSe2 Nanoparticles Encapsulated into Carbon Nanotubes with Enhanced Electron Conductance as Cathode for Rechargeable Magnesium Batteries

Jing Liu, Huilong Dong, Runjie Bi, Xiaowei Miao, Jun Yang, Hongbo Geng

Summary: In this study, Cu-doped CoSe2 nanoparticles encapsulated into carbon nanotubes (Cu-CoSe2@NC) were successfully synthesized through hydrothermal, selenization, and impregnation methods. The Cu-CoSe2@NC exhibited high reversible capacity and rate capability when used as cathode material for rechargeable magnesium batteries.

CHEMNANOMAT (2023)

Article Engineering, Environmental

A holomolecule conjugated and electron delocalized organic compound for superior proton-storage redox capability

Renwei Jing, Jing He, Lingtong Hu, Jun Yang, Chao Yan, Minjie Shi

Summary: This study synthesized a holomolecule-conjugated organic compound (PZQN) and demonstrated its fast, stable, and unrivaled proton-storage redox capability in APBs. The research also revealed the extraordinary electron delocalization in the PZQN molecule, confirming its superior electrochemical properties and promising application prospect.

CHEMICAL ENGINEERING JOURNAL (2023)

Article Chemistry, Physical

Compositing ultrafine CoFe2O4 spinel with porous silica as catalyst for photothermal PMS activation and interfacial water evaporation

Mengting Liu, Shulan Ma, Hongyao Zhao, Hao Lu, Jun Yang, Sheng Tang, Shuying Gao, Fu Yang

Summary: In this study, ultrafine plasmonic CoFe2O4 spinel nanoparticles were combined with porous silica to obtain bimetallic nanocomposites. The CoFe/SiO2-8 nanocatalysts showed significant active interfacial effects and better photothermal effects in the catalytic degradation of bisphenol A. Moreover, the introduction of SiO2 allowed higher activation efficiency of PMS and the potential possibility for the regeneration of freshwater from polluted water resource.

JOURNAL OF ALLOYS AND COMPOUNDS (2023)

Article Chemistry, Physical

Aliovalent doping and structural design of MoSe2 with fast reaction kinetics for high-stable sodium-ion half/full batteries

Jia Guo, Huilong Dong, Jing Liu, Jinpeng Guan, Kaiyang Li, Yubo Feng, Quan Liu, Jun Yang, Hongbo Geng

Summary: In this study, a novel aliovalent doping and structural engineering technique was used to prepare phosphorus-doped MoSe2@rGO composite. The material overcomes the limitations of MoSe2, such as agglomeration, poor electron conductance, and mechanical strain, improving the performance and durability of sodium-ion batteries.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2023)

Article Engineering, Environmental

Constructing functional thermal-insulation-layer on Co3O4 nanosphere for reinforced local-microenvironment photothermal PMS activation in pollutant degradation

Mengting Liu, Hongyang Zhu, Rongrong Du, Wuxiang Zhang, Weilong Shi, Zengjing Guo, Sheng Tang, Edison Huixiang Ang, Jun Yang, Jianming Pan, Fu Yang

Summary: Photothermal catalysis of functional materials triggered by light-irradiation to local heating approach attracts attention. The thermalconductive surface of functional materials directly contacting reaction solution easily delivers heat to the reaction system, leading to weakening heating effect. A functional low-thermal-conductivity layer that Mn-coupling porous SiO2 shell layer was constructed over the Co3O4 nanospheres. The introduction of Mn and structural remodeling through tailored annealing temperature can give improved catalytic hybrids abundant valence states and interfacial effects.

JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING (2023)

Article Chemistry, Physical

Structural regulation enabled stable hollow molybdenum diselenide nanosheet anode for ultrahigh energy density sodium ion pouch cell

Kang Xu, Juan Xie, Huilong Dong, Chencheng Sun, Yue Li, Jia Guo, Zhefei Wang, Jun Yang, Hongbo Geng

Summary: Hollow nanoboxes shaped carbon supported sulfur-doped MoSe2 nanosheets (S-MoSe2@NC) were fabricated as anode for sodium-ion batteries, showing high rate capability and excellent cycling stability. The structure with a rock-steady foundation and quick ion migration efficiently controlled sodium storage, paving the way for novel applications of high-performance transition metal dichalcogenides in sodium storage.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2024)

暂无数据