4.8 Article

Mechanochemical synthesis of high coercivity Nd2(Fe,Co)14B magnetic particles

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NANOSCALE
卷 9, 期 47, 页码 18651-18660

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ROYAL SOC CHEMISTRY
DOI: 10.1039/c7nr04703g

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  1. National Research Foundation (NRF) Singapore under the Corp Lab@University Scheme

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With increasing demand for magnets in energy conversion systems, the quest for the development and understanding of novel processing routes to produce permanent magnets has become urgent. We report a novel mechanochemical process for the synthesis of Nd-2(Fe, Co)(14)B magnetic particles with a high coercivity of 12.4 kOe. This process involves the reduction of neodymium oxide, iron oxide, cobalt oxide and boron anhydride in the presence of a calcium reducing agent and a CaO diluent. The formation mechanism of Nd-2(Fe, Co)(14)B changed with increasing CaO content, and the average crystal size of the Nd-2(Fe, Co)(14)B particles also increased, resulting in an increase in the coercivity values. The reaction mechanism during milling was revealed through a study of the phase transformations as a function of milling time. It was found that unlike self-propagating reactions, this reduction reaction during milling requires continuous input of mechanical energy to reach a steady state.

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