4.5 Article

Reduced Graphene Oxide/Carbon Nanotube/Gold Nanoparticles Nanocomposite Functionalized Screen-Printed Electrode for Sensitive Electrochemical Detection of Endocrine Disruptor Bisphenol A

期刊

ELECTROANALYSIS
卷 27, 期 11, 页码 2527-2536

出版社

WILEY-V C H VERLAG GMBH
DOI: 10.1002/elan.201500120

关键词

Environmental monitoring; Food safety; Graphene; Electrodeposition; Electrochemical reduction; Electrochemical sensor

资金

  1. National Institute of Food and Agriculture, United States Department of Agriculture [WISO1644]
  2. UW MRSEC [DMR-1121288]
  3. UW NSEC [DMR-0832760]
  4. Wisconsin Distinguished Graduate Fellowship
  5. Sigma Xi, The Scientific Research Society [497166]
  6. Technological Research Council of Turkey [2219]
  7. Division Of Materials Research
  8. Direct For Mathematical & Physical Scien [0832760] Funding Source: National Science Foundation

向作者/读者索取更多资源

We fabricated a highly sensitive electrochemical sensor for the determination of bisphenol A (BPA) in aqueous solution by using reduced graphene oxide (RGO), carbon nanotubes (CNT), and gold nanoparticles (AuNPs)-modified screen-printed electrode (SPE). GO/CNT nanocomposite was directly reduced to RGO/CNT on SPE at room temperature. AuNPs were then electrochemically deposited in situ on RGO/CNT-modified SPE. Under optimized conditions, differential pulse voltammetry (DPV) produced linear current responses for BPA concentrations of 1.45 to 20 and 20 to 1,490 nM, with a calculated detection limit of an ultralow 800 pM. The sensor response was unaffected by the presence of interferents such as phenol, p-nitrophenol, pyrocatechol, 2,4-dinitrophenol, and hydroquinone.

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