Article
Environmental Sciences
J. Vinoth Kumar, G. Kavitha, Gadah Albasher, Maryium Sajjad, R. Arulmozhi, M. Komal, M. Sherlin Nivetha, N. Abirami
Summary: In this study, multiplex heteroatoms doped carbon dots were synthesized from Tinospora cordifolia miers plant extract using a simple hydrothermal approach. Their catalytic activity towards dyes and potential applications for anti-spurious purposes were evaluated. The synthesized carbon dots exhibited tunable fluorescence and high quantum yield, suggesting their potential as catalysts and security labels.
Article
Chemistry, Multidisciplinary
Nandan Ghorai, Soumyadip Bhunia, Subham Burai, Hirendra N. Ghosh, Pradipta Purkayastha, Somen Mondal
Summary: This study synthesized and separated C-Dots with different emission peaks and investigated their carrier dynamics to reveal the origin and control mechanism of their fluorescence properties. These findings are of great significance for the design and development of new architectures based on C-Dots.
Article
Chemistry, Physical
Bony K. John, Sneha Mathew, Neenamol John, Jincy Mathew, Beena Mathew
Summary: In this paper, blue-emitting N,S-doped carbon quantum dots were synthesized and characterized. They were successfully used for the detection of tartrazine in soft drinks and candies using fluorescence and electrochemical methods. In addition, a fluorescent ink based on N, S-CQDs was developed for writing, drawing, and fingerprint imaging applications.
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY
(2023)
Article
Chemistry, Multidisciplinary
Pengfei Fan, Can Liu, Congcong Hu, Feifei Li, Xi Lin, Shengyuan Yang, Fubing Xiao
Summary: In this study, iron-doped carbon dots were synthesized using a green method and demonstrated dual-signal detection of ascorbic acid through colorimetric and fluorometric assays. The presence of iron-doped carbon dots enabled the oxidation of TMB and subsequent reduction by ascorbic acid, leading to a reversible fluorescence response. The method showed promising application prospects in accurate detection of ascorbic acid with complementary signals to improve reliability.
NEW JOURNAL OF CHEMISTRY
(2022)
Article
Chemistry, Multidisciplinary
Pengfei Fan, Can Liu, Congcong Hu, Feifei Li, Xi Lin, Fubing Xiao, Hao Liang, Le Li, Shengyuan Yang
Summary: N,S-CDs with strong orange fluorescence were synthesized through a hydrothermal method, showing excitation-independent photoluminescent behavior and excellent stability. A label-free and sensitive detection method for VB12 in drugs was established based on the inner filter effect between VB12 and N,S-CDs.
NEW JOURNAL OF CHEMISTRY
(2022)
Article
Chemistry, Analytical
Linhong Liao, Xiao Lin, Kai Wang, Zhiyuan Hu, Fengshou Wu
Summary: The preparation of nitrogen and sulfur co-doped carbon dots (N, S-CDs) with highly bright orange-red fluorescence is reported. The N, S-CDs exhibited superior properties, including intense long-wavelength emission, high fluorescence quantum yield, and excellent water dispersibility. Furthermore, the N, S-CDs showed potential applications in fluorescence detection and anti-counterfeiting due to their facile preparation, intense fluorescence, high stability, easy processing, and selective fluorescence change for specific analytes.
Article
Spectroscopy
Linlin Wang, Jayasmita Jana, Jin Suk Chung, Seung Hyun Hur
Summary: High quantum yield GAAP-CDs were synthesized using a simple hydrothermal route and utilized as sensing probes for toxic hypochlorite. The synthesized CDs demonstrated low detection limits and excellent selectivity towards ClO- ions, making them promising candidates for ClO- detection in tap water and drinking water samples.
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
(2021)
Article
Chemistry, Physical
Srijon Ghosh, Arnab Ghosh, Goutam Ghosh, Kritiman Marjit, Amitava Patra
Summary: The study revealed structural modifications and changes in ultrafast relaxation dynamics of red-emitting C-dots due to boron doping. Boron doping increased the percentage of pyrridinic nitrogen and formed an additional excited state level, slowing down the initial relaxation process and prolonging the overall lifetime of the C-dots.
JOURNAL OF PHYSICAL CHEMISTRY LETTERS
(2021)
Article
Materials Science, Biomaterials
Jieqiang Tan, Shili Zhao, Junyu Chen, Xiaoqin Pan, Chen Li, Yingliang Liu, Caijuan Wu, Wei Li, Mingtao Zheng
Summary: Nanotechnology is an effective way to stimulate crop yield potential, and nitrogen-doped carbon dots have significant promotive effects on lettuce biomass and quality, improving photosynthesis and nitrogen metabolism.
JOURNAL OF MATERIALS CHEMISTRY B
(2023)
Article
Biotechnology & Applied Microbiology
D. A. Todorenko, D. A. Gvozdev, G. V. Tsoraev, A. A. Baizhumanov, E. P. Lukashev, D. N. Matorin
Summary: Carbon dots are a new type of carbon-based material with unique properties that are attractive for various applications. However, their widespread production and formation as by-products lead to environmental pollution. The effects of carbon dots on microalgae were studied, and it was found that they did not induce oxidative stress or affect photosynthetic activity. However, they did reduce the growth rate of microalgae by shading them. These results contribute to the understanding of the interaction between carbon dots and microalgae.
JOURNAL OF APPLIED PHYCOLOGY
(2023)
Review
Biochemistry & Molecular Biology
Joanna Szczepankowska, Gohar Khachatryan, Karen Khachatryan, Magdalena Krystyjan
Summary: This review discusses the types and methods of obtaining carbon dots, as well as their potential applications in biotechnology and food technology.
INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES
(2023)
Article
Chemistry, Multidisciplinary
Vanessa Michaud, Jonas Pracht, Fabian Schilfarth, Cornelia Damm, Benedikt Platzer, Philipp Haines, Christina Harreiss, Dirk M. Guldi, Erdmann Spiecker, Wolfgang Peukert
Summary: Carbon dots (CDs) are highly fluorescent materials used in bioimaging, sensors, and luminescent displays. This study successfully separated all components of CDs by two-step gradient chromatography, showing that amorphous and crystalline CDs coexist in the same suspension. High performance liquid chromatography (HPLC) was used to further improve purification efficiency and automate the process, achieving separation of up to six components.
Article
Nanoscience & Nanotechnology
Zhilin Zhou, Zhiwen Li, Jianghua Wang, Zhichuan Wu, Yingqiang Fu
Summary: In this study, blue emitting nitrogen-doped carbon quantum dots (NCQDs) were successfully synthesized using a hydrothermal method, and a fluorescence assay for azithromycin detection was developed based on the quenching effect of azithromycin and Cu2+ on the fluorescence of N-CQDs.
Article
Chemistry, Physical
C. Russo, B. Apicella, A. La Rocca, M. Sirignano
Summary: Flame synthesis is a controllable method for producing carbon dots with tunable emission properties. The equivalence ratio plays a significant role in the production of carbon dots with different emission spectra, and it is a powerful and simple tool for large-scale synthesis.
Article
Chemistry, Physical
Parisa Mohammad-Jafarieh, Rahman Salamat-Ahangari, Mohammad Pourhassan-Moghaddam, Abolfazl Akbarzadeh
Summary: In this study, carbon dots were synthesized inexpensively from persimmon peel biowaste, characterized and found to possess excellent optical properties and dispersibility. The carbon dots can serve as a nanoprobe for medium polarity and a fluorescent chemical sensing platform for metal ions.
JOURNAL OF MOLECULAR LIQUIDS
(2021)
Article
Computer Science, Interdisciplinary Applications
Rabar H. Faraj, Azad A. Mohammed, Ahmed Mohammed, Khalid M. Omer, Hemn Unis Ahmed
Summary: The study proposed three different models to predict the compressive strength of self-compacting concrete mixtures with or without nano-silica, and found that the multi-logistic model (MLR) outperformed other models for forecasting performance; sensitivity analysis demonstrated that curing time is the most influencing variable for predicting the compressive strength of self-compacting concrete modified with nano-silica.
ENGINEERING WITH COMPUTERS
(2022)
Article
Plant Sciences
Yousef Sohrabi, Khalid M. Omer, Majed Yazdani, Firuze Sharifi Kalyani
Summary: This research investigated the effect of a new nano-fertilizer derived from Paulownia on the morpho-physiological traits of green basil plants under drought stress conditions. The results showed that spraying the nano-fertilizer improved plant growth and increased yield.
JOURNAL OF PLANT NUTRITION
(2023)
Article
Nanoscience & Nanotechnology
Azad H. Alshatteri, Gona K. Ali, Khalid M. Omer
Summary: The objective of this study is to develop a smartphone-assisted visual detection sensor using cerium-doped strontium-based metal-organic frameworks as peroxidase-like nanozymes for the rapid, low-cost, on-site detection of total antioxidant capacity (TAC). The results show that the Ce-SrMOFs can effectively detect the concentration of antioxidants. This method provides accurate and reliable results for measuring TAC in saliva samples from lung cancer patients.
ACS APPLIED MATERIALS & INTERFACES
(2023)
Article
Construction & Building Technology
Rabar H. Faraj, Azad A. Mohammed, Khalid M. Omer
Summary: The addition of an optimum percentage of NS particles can significantly restore most properties of RPASCC which were degraded due to the addition of RPAs. This technique allows the construction industry to safely use RPAs in SCC mixtures without concerns about their negative impact on concrete performance.
CONSTRUCTION AND BUILDING MATERIALS
(2023)
Article
Environmental Sciences
A. A. Goyi, N. M. Sher Mohammad, K. M. Omer
Summary: This study investigates the potential of potato peel waste powder as a biomass feedstock for hydrothermal carbonization to produce hydrochar, which can be used as an adsorbent for water treatment. The physicochemical properties of potato peel hydrochar were compared to potato peel waste powder using various characterization techniques. The results demonstrate that potato peel hydrochar has a higher specific surface area and adsorption capacity for Congo red, making it a viable adsorbent for water treatment. The study emphasizes the potential of waste biomass, such as potato peel, to produce hydrochar as an effective and sustainable adsorbent for water treatment.
INTERNATIONAL JOURNAL OF ENVIRONMENTAL SCIENCE AND TECHNOLOGY
(2023)
Article
Chemistry, Analytical
Azad H. Alshatteri, Khalid M. Omer
Summary: Ratiometric-based dual-emission fluorescence probe constructed by a dual-nanocluster was used to measure the amount of cysteine. The addition of cysteine caused a noticeable fluorescence color shift from red to blue. The probe showed satisfactory accuracy and precision in measuring cysteine in human serum.
MICROCHEMICAL JOURNAL
(2023)
Article
Spectroscopy
Shano M. Pirot, Khalid M. Omer, Azad H. Alshatteri, Gona K. Ali, Omer B. A. Shatery
Summary: In this research, a dual-template molecularly imprinted polymer surface was prepared on a blue fluorescent Cr-based MOF functionalized with yellow emissive carbon dots (Y-CDs), using L-ascorbic acid (AA) and uric acid (UA) as templates for simultaneous selective recognition of AA and UA. The developed nanocomposite probe (Y-CDs/Cr-MOF@MIP) contains two recognition site cavities and emits dual fluorescence spectra - blue emission from Cr-MOF and yellow emission from Y-CDs. The quenching of Y-CDs' yellow fluorescence and Cr-MOF's blue fluorescence in the presence of AA and UA, respectively, allows for the design of a dual-template biosensor for simultaneous detection of AA and UA. The sensor displayed a dynamic linear response and high selectivity and sensitivity for AA and UA detection in human urine samples.
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
(2023)
Article
Chemistry, Analytical
Sameera Sh Mohammed Ameen, Nidhal M. Sher Mohammed, Khalid M. Omer
Summary: In this study, ultra-small and highly fluorescent zinc-based metal-organic frameworks (FMOF-5) were synthesized, which have the characteristics of stability, low cost, and robustness, making them highly desirable in bioanalytical applications. By selectively tuning the emission color and enhancing the fluorescence intensity of FMOF-5 through aggregation induced emission (AIE), tetracycline (TC) was successfully detected with high sensitivity. The integration of a smartphone and a visual platform enabled quantitative point-of-care testing. The results of this study have promising implications for practical applications.
Article
Nanoscience & Nanotechnology
Sameera Sh Mohammed Ameen, Faroq Omer Qasim, Huda S. Alhasan, Kosar H. Aziz, Khalid M. Omer
Summary: Dual-state emitters (DSEs) exhibit fluorescence in both the solution and solid state, and can be used in various fields. We synthesized a stable blue-emitting zinc-based MOF with rodlike nanostructures (UoZ-2), which showed intrinsic DSE. By adding tetracycline (TC), the color of UoZ-2 changed from blue to greenish-yellow, and the fluorescence intensity was dramatically enhanced due to aggregation induced emission (AIE). A sensitive ratiometry-based visual detection platform for TC was designed using the DSE and AIE properties of UoZ-2 alone and UoZ-2:TC, with a detection limit of 4.5 nM.
ACS APPLIED MATERIALS & INTERFACES
(2023)
Article
Chemistry, Multidisciplinary
Rebaz F. F. Hamarawf, Dyari I. I. Tofiq, Khalid M. M. Omer
Summary: Green synthesis methods for inorganic nanomaterials have gained attention for their effectiveness and suitability for large-scale production. In this study, M-type manganese-substituted strontium hexaferrite nanoparticles were successfully synthesized using chemical and green-based sol-gel auto-combustion routes. The antibacterial activity of the synthesized nanoparticles was examined, with the findings suggesting that the high magnetic characteristics, small particle size, large surface area, and mesoporous properties of SMHF-P contribute to its increased antibacterial activity.
NEW JOURNAL OF CHEMISTRY
(2023)
Review
Chemistry, Multidisciplinary
Kosar Hikmat Hama Aziz, Fryad S. Mustafa, Khalid M. Omer, Sarkawt Hama, Rebaz Fayaq Hamarawf, Kaiwan Othman Rahman
Summary: Heavy metal contamination of water sources is a global environmental concern due to industrialization, climate change, and urbanization. This pollution threatens aquatic ecosystems and human health through toxic and bioaccumulative heavy metal ions. Efforts have been made to find cost-effective methods for wastewater treatment, such as physicochemical adsorption and advanced oxidation processes. However, practical applications may be limited by high preparation and usage costs. This review focuses on the sources, transformations, toxicological impacts, and removal techniques of heavy metal pollution.
Article
Chemistry, Multidisciplinary
Shinwar A. Idrees, Lazgin A. Jamil, Khalid M. Omer
Summary: In order to efficiently remove pharmaceutical wastes, novel photo-Fenton catalysts, iron-decorated boron nitride quantum dots (Fe@BNQDs), were prepared. Fe@BNQDs were characterized using XRD, SEM-EDX, FTIR, and UV-Vis spectrophotometry. The decoration of Fe on the surface of BNQDs enhanced the catalytic efficiency in the photo-Fenton process. The study investigated the photo-Fenton catalytic degradation of folic acid under UV and visible light, and the effects of H2O2, catalyst dose, and temperature on the degradation yield using Response Surface Methodology. The efficiency, kinetics, and mechanism of the photocatalysts were also studied, revealing the importance of holes and BNQDs in the degradation mechanism and the medium effect of active species such as e(-) and O-2(-). Computational simulation provided further insights into the fundamental process.
Article
Nanoscience & Nanotechnology
Sameera Sh Mohammed Ameen, Faroq Omer Qasim, Huda S. Alhasan, Kosar H. Aziz, Khalid M. Omer
Summary: Dual-state emitters (DSEs) are entities that exhibit fluorescence in both solution and solid state, opening up possibilities for various applications. This study reports a stable intrinsic dual-state blue emission zinc-based MOF that can detect tetracycline using color changes and enhanced fluorescence. The ratiometry-based paper sensor shows reliable quantification of tetracycline.
ACS APPLIED MATERIALS & INTERFACES
(2023)
Article
Chemistry, Analytical
Azad H. Alshatteri, Khalid M. Omer
Summary: The development of fluorescent probes for biomolecule detection is crucial for clinical diagnosis and bioanalysis. In this study, a novel fluorescent probe based on yellow emissive carbon dots (Y-CDs) was synthesized and used for sensitive and selective detection of bilirubin. The probe showed great selectivity for bilirubin and could be detected using a smartphone and computer software. The method has the potential to be used as a fast detection method for bilirubin in biological samples at the bedside.
ANALYTICAL METHODS
(2022)
Article
Chemistry, Multidisciplinary
Kawan F. Kayani, Khalid M. Omer
Summary: The synthesis of a red luminescent Eu-MOF for detecting folic acid in pharmaceutical formulations has been reported. The Eu-MOF showed stable red emission fluorescence and was used for quantitative detection of folic acid in solution and on paper strips.
NEW JOURNAL OF CHEMISTRY
(2022)