期刊
MICROCHIMICA ACTA
卷 184, 期 7, 页码 2411-2418出版社
SPRINGER WIEN
DOI: 10.1007/s00604-017-2247-7
关键词
Electroanalysis; Cyclic voltammetry; Electrochemical impedance spectroscopy; Conducting polymer; Electropolymerization; Nitrite detection
资金
- Natural Science Foundation of Shandong Province of China [ZR2016BM05]
- Shandong Province Key Research and Development Project [2016GNC112016]
A glassy carbon electrode (GCE) was modified with graphene oxide-doped polypyrrole (PPy), and flower-like cobalt nanostructures were then deposited on GCE by electrochemical reduction. The modified electrode shows improved catalytic behavior towards nitrite oxidation as the result of the nanoporous structure and the synergistic effect between cobalt nanostructures and GO/PPy. It is found that the amperometric oxidation current at 0.80 V (vs SCE) is about 2.5 times larger than that of a GCE modified with carbon nanotubes. Under optimum conditions, the modified electrode displays a linear range that extends over the 1.0 mu M to 3.2 mM and 6.8 - 12 mM concentration ranges, a lower detection limit of 15 nM (at an S/N ratio of 3), and a response time of 1 s. The modified electrode is adequately selective, highly stable and highly reproducible. The method was successfully applied to the determination of nitrite in pickled radish.
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