期刊
MATERIALS CHARACTERIZATION
卷 131, 期 -, 页码 168-174出版社
ELSEVIER SCIENCE INC
DOI: 10.1016/j.matchar.2017.05.013
关键词
Stainless steel; TEM; STEM-EDX; Passive film; Transpassive film; Secondary passive film
类别
资金
- SUG (Start-up funding in NTU) [COE_SUG/RSS_20AUG10_11/14]
- Tier 1 (ACRF grant MOE Singapore) [M401992]
- Tier 2 (ACRF grant MOE Singapore) [M4020159]
- Chinese Natural Science Foundation [51271031, 50701006]
- National Basic Research Program [2014CB643300]
Evolution of the oxide films formed on the surface of 316 stainless steel needles during the electrochemical polarization in 0.1 M NaOH solution is investigated by transmission electron microscopy (TEM) and energy dispersive X-ray spectroscopy (EDX). During the polarization process, the films can grow from 4 nm to dozens of nanometers and are composed of crystalline structures incorporated with amorphous phases. Additionally, Cr (III) species that are formed at low potentials will transform into Cr (VI) species in secondary passive region. Fe element is present as Fe3O4-like spinel oxides while no Fe2O3 is found in the films. The Fe/Cr ratio increases with the increase of applied potential.
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