4.4 Article

Enhanced inhibition of steel corrosion by L-cysteine under visible-light illumination

期刊

出版社

WILEY-V C H VERLAG GMBH
DOI: 10.1002/maco.201609386

关键词

corrosion inhibitor; L-cysteine; low-alloy steel; visible light

资金

  1. China University of Petroleum (Beijing) [2462015YQ0602, YJRC-2013-45]
  2. National Natural Science Foundation of China [51301199]

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The heteroatoms such as nitrogen, oxygen, and sulfur of organic inhibitor play a crucial role on its corrosion inhibition behavior. In order to reveal their adsorption behavior and inhibition performance under illumination condition on steel surface, this study selects L-cysteine as study object. On the basis of electrochemical measurement, surface analysis, and theoretical calculation, a promising increase in corrosion inhibition efficiency is observed when visible-light is impinged on steel surface in sodium chloride solution with L-cysteine. The enhanced performance is attributed to the sample surface photovoltaic effect, thereby facilitating both the thiol and the amino groups to tilt toward the surface.

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