Article
Engineering, Biomedical
Dae Hyun Cho, Thomas Avey, Kyoung Hyup Nam, David Dean, Alan A. Luo
Summary: In this study, biodegradable Mg-Zn-Ca-Mn alloys were prepared by squeeze casting, and it was found that increasing Mn content can improve the microstructure and corrosion resistance of the alloys. Samples with Mn showed the best mechanical properties and biocompatibility.
ACTA BIOMATERIALIA
(2022)
Article
Materials Science, Ceramics
Yangping Chen, Wei Li, Wei Wang, Yun Zhao, Minfang Chen
Summary: A one-step hydrothermal treatment was used to deposit a nano silver-loaded magnesium-aluminum hydrotalcite coating on the surface of a Mg-Zn-Ca alloy, improving corrosion resistance and antibacterial properties. Optimizing preparation conditions resulted in smaller silver particles, reduced corrosion rate, and excellent antibacterial and biocompatibility performance.
CERAMICS INTERNATIONAL
(2022)
Article
Metallurgy & Metallurgical Engineering
Bao-sheng Liu, Miao-miao Cao, Yue-zhong Zhang, Yong Hu, Chang-wei Gong, Li-feng Hou, Ying-hui Wei
Summary: The addition of minor amounts of Ca in Mg-6Zn-0.3Mn alloy can refine the grains slightly and improve strength, with the alloy containing 0.5 wt.% Ca showing the best mechanical properties. However, increasing Ca content deteriorates the corrosion resistance of the alloys, while positively impacting cell viability and antibacterial activity.
TRANSACTIONS OF NONFERROUS METALS SOCIETY OF CHINA
(2021)
Article
Chemistry, Physical
Yang Zhao, Han Li, Chaojie Jing, Fangchao Zhao, Dingfei Zhang, Fusheng Pan
Summary: The effects of various Gd additions on the microstructure evolution, tensile properties, and corrosion resistance of Mg-6Zn-0.5Ca-1Mn (ZMX6105) alloys were examined. The addition of Gd promoted the formation of Ca2Mg6Zn3 phase during solidification and inhibited dynamic recrystallization, resulting in the refinement of dynamic recrystallized grains and strengthening of basal texture. Additionally, the ZMX6105-0.2Gd alloy exhibited excellent tensile properties and optimal corrosion resistance in a 3.5 wt% NaCl solution.
Article
Chemistry, Applied
Jinhe Dou, Jing Wang, Yupeng Lu, Chuanzhong Chen, Huijun Yu, Robin Lok-Wang Ma
Summary: The generation of MAO/CS composite coatings on Mg-1.75Zn-0.56Ca alloy surface significantly improves the corrosion resistance and biocompatibility of the alloy, with smooth and defect-free characteristics of the coatings.
PROGRESS IN ORGANIC COATINGS
(2021)
Article
Materials Science, Multidisciplinary
Bing-Yu Wang, Mei-Xuan Li, Yi-Jia Li, Yu-Fei Wang, Yipeng Gao, Hui-Yuan Wang
Summary: Lean Mg-1.2Zn-0.3Ca-0.3Al-xMn (x = 0.25, 0.38, 0.5 wt%) alloys with different Al/Mn ratios were prepared using twin-roll casting technique. The formation of rhombohedral Al8Mn5 or cubic beta-Mn depended on the Al/Mn ratio. The alloy with Al/Mn>1.6 exhibited the lowest average corrosion rate (4.55 mm y-1) due to the lower Volta potential of Al8Mn5 compared to beta-Mn. The presence of fine Al8Mn5 weakened micro-galvanic corrosion and reduced stress concentration, resulting in admirable corrosion resistance and mechanical properties (UTS: -266 MPa, YS: -193 MPa, EF: -20%) for the alloy with Al/Mn>1.6.
Article
Materials Science, Multidisciplinary
Milad Johari, Seyed Hadi Tabaian, Shahaboddin Saeedi
Summary: This study investigated the influence of heat-treatment and anodizing procedures on microstructure evolution and corrosion performance of two magnesium alloys with different Ca and rare earth element contents but the same Zn content. Results showed that corrosion performance is affected by both chemical composition and heat-treatment procedures. Anodizing process on the solution heat-treated F1 alloy led to a significant reduction in corrosion rate.
METALS AND MATERIALS INTERNATIONAL
(2022)
Article
Materials Science, Multidisciplinary
Pingping Jia, Yaokun Pan, Lang Yu, Jingtao Wang, Rui Feng, Yongxiao Wang, Xiaoying Fang, Chuanzhong Chen
Summary: This study focuses on the preparation of biodegradable calcium phosphate (CaP) ceramic coatings on self-designed Mg-2.0Zn-0.6Ca-xSi alloys through plasma electrolytic oxidation (PEO). The influence of calcium (Ca) and silicon (Si) on alloy microstructure, coating formation, and biomineralization mechanisms were investigated. The in vitro bioactivity and degradability of the CaP coatings were evaluated through immersion tests. The results suggest that the microstructure of the Mg-2.0Zn-0.6Ca-xSi alloys can affect the formation and growth of PEO coatings.
JOURNAL OF MATERIALS RESEARCH AND TECHNOLOGY-JMR&T
(2023)
Article
Nanoscience & Nanotechnology
Nikolaus P. Papenberg, Aurel Arnoldt, Bernhard Trink, Peter J. Uggowitzer, Stefan Pogatscher
Summary: This study investigates the forging process of a heat-treatable magnesium alloy AXMZ1000 for a piston rod. The microstructural evolution and mechanical properties of two different stock materials, cast and extruded, are compared and analyzed. The results show that comparable microstructures are obtained with both starting materials, and the mechanical properties achieved with extruded feedstock are slightly better.
MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING
(2022)
Article
Chemistry, Physical
T. Nakata, C. Xu, Nurul Aliea Syafiqa binti Osman, L. Geng, S. Kamado
Summary: By investigating the effects of Al content on the mechanical properties, formability, and corrosion resistance of magnesium alloy sheets, it was found that moderate Al addition significantly improves these properties, resulting in good overall performance of the alloy sheets.
JOURNAL OF ALLOYS AND COMPOUNDS
(2022)
Article
Metallurgy & Metallurgical Engineering
Xiyu Yao, Jincheng Tang, Yinghao Zhou, Andrej Atrens, Matthew S. Dargusch, Bjoern Wiese, Thomas Ebel, Ming Yan
Summary: Utilizing selective laser melting (SLM) for surface modification of magnesium alloys can simultaneously improve corrosion behavior and microhardness, reducing corrosion rate and increasing microhardness while maintaining good biocompatibility. This approach demonstrates the potential of SLM for developing advanced biomedical magnesium alloys.
JOURNAL OF MAGNESIUM AND ALLOYS
(2021)
Article
Engineering, Biomedical
Bo Yuan, Hewei Chen, Rui Zhao, Xuangeng Deng, Guo Chen, Xiao Yang, Zhanwen Xiao, Antoniac Aurora, Bita Ana Iulia, Kai Zhang, Xiangdong Zhu, Antoniac Vasile Iulian, Shen Hai, Xingdong Zhang
Summary: This study developed a novel nanocomposite coating on the surface of magnesium alloy using a combined strategy. The coating showed high bonding strength, hydrophilicity, and corrosion resistance. It improved antibacterial activity, promoted osteogenic differentiation of cells, and facilitated bone regeneration. This research provides a promising surface modification strategy for developing multifunctional magnesium-based implants.
BIOACTIVE MATERIALS
(2022)
Article
Metallurgy & Metallurgical Engineering
M. Kavyani, G. R. Ebrahimi, H. R. Ezatpour, M. Jahazi
Summary: This study investigated the microstructural evolution, mechanical properties, and biocorrosion performance of a Mg-Zn-Ca-Mn alloy under different processing conditions. The results showed that the alloy experienced grain refinement, improved mechanical properties, and enhanced biocorrosion resistance after undergoing the HECAP process. These findings suggest that HECAPed Mg-Zn-Ca-Mn alloy has great potential for biomedical applications.
JOURNAL OF MAGNESIUM AND ALLOYS
(2022)
Article
Materials Science, Multidisciplinary
T. Nakata, C. Xu, R. Abe, L. Geng, S. Kamado
Summary: The reheating at high temperature was used to control the textural features in a rolled Mg-Zn-Ca-Mn alloy sheet. Reheating at 450 degrees C caused grain coarsening, leading to the formation of double twinning and shear bands during rolling. Unexpectedly, the basal texture became strong due to the non-uniformly distributed dislocations. On the other hand, reheating at 350 degrees C resulted in uniform deformation-microstructure and apparent texture weakening during post-annealing.
MATERIALS CHARACTERIZATION
(2023)
Article
Materials Science, Multidisciplinary
Devadas Bhat Panemangalore, Rajashekhara Shabadi, Manoj Gupta
Summary: This study investigates the effect of calcium and erbium on magnesium-zinc alloy properties, finding that the addition of erbium reduces grain size and enhances mechanical and corrosion resistance. The quaternary alloy shows the highest strength and elongation due to twin structures. The addition of alloying elements also reduces degradation rates.
Article
Polymer Science
Targol Hashemi, Mohammad Reza Mehrnia, Aydin Marandi, Ahmad Fauzi Ismail
Summary: Novel mixed matrix membranes were prepared using magnetic casting and nanocomposite technology, resulting in increased water flux and improved anti-fouling properties.
JOURNAL OF APPLIED POLYMER SCIENCE
(2023)
Article
Engineering, Biomedical
N. Nazemi, N. Rajabi, Z. Aslani, M. Kharaziha, M. Kasiri-Asgarani, H. R. Bakhsheshi-Rad, A. Najafinezhad, A. F. Ismail, S. Sharif, F. Berto
Summary: ZSM-5 scaffolds fabricated with the space holder method exhibit excellent porosity, mechanical properties, bioactivity, and antibacterial properties, showing potential application in bone tissue engineering.
JOURNAL OF BIOMATERIALS APPLICATIONS
(2023)
Review
Metallurgy & Metallurgical Engineering
Farzad Badkoobeh, Hossein Mostaan, Mahdi Rafiei, Hamid Reza Bakhsheshi-Rad, Seeram RamaKrishna, Xiongbiao Chen
Summary: Magnesium-based materials have the unique ability to biodegrade within the human/animal body, making them suitable for fabricating surgical bioimplants. Additive manufacturing (AM) and three-dimensional (3D) printing are promising techniques for bioimplant design and manufacturing, despite challenges related to the properties of magnesium-based alloys. This review article critically examines various AM processes, mechanical and biocompatible properties, as well as the challenges and possibilities of magnesium-based implants.
JOURNAL OF MAGNESIUM AND ALLOYS
(2023)
Article
Engineering, Biomedical
F. Safarpour, M. Kharaziha, H. Mokhtari, R. Emadi, H. R. Bakhsheshi-Rad, Seeram Ramakrishna
Summary: Biological materials, such as cell-derived membrane vesicles, have been used as alternative sources for molecular delivery systems due to their multicomponent features and easy-to-carry therapeutic agents. In this study, a red blood cell membrane (RBCM) vesicle-laden methacrylate kappa-carrageenan (KaMA) composite hydrogel was developed for soft tissue engineering. The hybrid hydrogels exhibited modified characteristics based on the content of RBCM vesicles, and showed controlled release of a hydrophobic drug molecule and support for cell growth.
BIOMEDICAL MATERIALS
(2023)
Article
Environmental Sciences
Noresah Said, Woei Jye Lau, Muhammad Nidzhom Zainol Abidin, Amir Mansourizadeh, Ahmad Fauzi Ismail
Summary: In this study, poly(citric acid)-grafted graphene oxide (PGO) was incorporated into single-layer hollow fiber (SLHF) and dual-layer hollow fiber (DLHF) membranes to improve their antifouling properties during water treatment. The optimized PGO loading of 0.7 wt% in SLHF membrane resulted in higher water permeability and bovine serum albumin rejection compared to the neat membrane. Similarly, introducing 0.7 wt% PGO only to the outer layer of DLHF membrane improved its antifouling properties and increased the rejection rate of bovine serum albumin to 97.7%.
ENVIRONMENTAL TECHNOLOGY
(2023)
Review
Materials Science, Multidisciplinary
Vahid Monfared, Hamid Reza Bakhsheshi-Rad, Mahmood Razzaghi, D. Toghraie, Maboud Hekmatifar, Filippo Berto
Summary: This article provides a brief review of the creep behavior of nanocomposites-based materials in recent years. Investigating the time-dependent plastic deformation of nanocomposites is crucial in modern sciences. The study of creep is important for applications under high temperature and high stresses, such as turbine blades, spaceships, shuttles, and nozzle guide vanes. Additionally, the article presents a detailed review of the creep behavior of metal-based nanocomposites, particularly magnesium-based ones, and suggests the use of nanoparticle encapsulation to improve their creep resistance.
METALS AND MATERIALS INTERNATIONAL
(2023)
Article
Chemistry, Multidisciplinary
A. Sumisha, G. Arthanareeswaran, A. F. Ismail
Summary: This study mainly focuses on the analysis of casein protein transport characteristics through ultrafiltration membranes. Polysulfone-based polymer membranes modified with different materials are used. The experimental results show that the transport of casein is controlled by convection.
SEPARATION SCIENCE AND TECHNOLOGY
(2023)
Article
Engineering, Biomedical
Erik Pagan, Evan Stefanek, Amir Seyfoori, Mahmood Razzaghi, Behnad Chehri, Ali Mousavi, Pietro Arnaldi, Zineb Ajji, Daniela Ravizzoni Dartora, Seyed Mohammad Hossein Dabiri, Anne Monique Nuyt, Ali Khademhosseini, Houman Savoji, Mohsen Akbari
Summary: In situ bioprinting is a versatile technology for tissue repair and restoration through site-specific delivery of pro-healing constructs. we developed a low-priced handheld bioprinter that allows exquisite control over the physical and chemical properties of deposited bioinks. The handheld printer can produce multi-component fibers with different cross-sectional shapes and material compositions, and also has the capability for drug delivery and biosensor production.
Article
Chemistry, Physical
Mohammad Taher Amirzade-Iranaq, Mahdi Omidi, Hamid Reza Bakhsheshi-Rad, Abbas Saberi, Somayeh Abazari, Nadia Teymouri, Farid Naeimi, Claudia Sergi, Ahmad Fauzi Ismail, Safian Sharif, Filippo Berto
Summary: This study aims to synthesize MgZn/TiO2-MWCNTs composites with varying TiO2-MWCNT concentrations and investigate their mechanical, corrosion, and antibacterial properties. The results showed enhanced microhardness and compressive strength in the composites compared to the MgZn composite. Cell culture experiments demonstrated increased osteoblast proliferation and attachment with the addition of TiO2-MWCNTs, while corrosion resistance and degradation rate were also improved in the Mg-based composite. Antibacterial evaluations revealed that the composite showed antibacterial activity against Staphylococcus aureus. The MgZn/TiO2-MWCNTs composite has great potential for use in orthopedic fracture fixation devices.
Article
Polymer Science
Mahmood Razzaghi, Amir Seyfoori, Erik Pagan, Esfandyar Askari, Alireza Hassani Najafabadi, Mohsen Akbari
Summary: To address the need for continuous monitoring and treatment adjustments in chronic diseases, a microneedle array technique is proposed to extract interstitial skin fluid (ISF) painlessly and bloodlessly. The molecular composition of ISF resembles blood plasma, making it a good choice for biomarker identification. The integration of a multiplexed sensor in the microneedle array enables rapid biomarker detection, allowing for practical and self-administrable monitoring and management of metabolic diseases.
Article
Engineering, Chemical
Komathi Kannathasan, Juhana Jaafar, Nuor Sariyan Suhaimin, Nurul Natasha Mohammad Jafri, Sadaki Samitsu, N. H. Alias, A. F. Ismail, T. Matsuura, M. H. D. Othman, Mukhlis A. Rahman, Farhana Aziz, Norhaniza Yusof, Mohammed Rasool Qtaishat, M. I. Ismail
Summary: A novel method of fabricating translucent photocatalytic membrane using a modified morphological structure as a photocatalyst has been developed. The study highlights the effect of translucency on the efficiency of photocatalytic reactions.
CHEMICAL ENGINEERING RESEARCH & DESIGN
(2023)
Article
Engineering, Environmental
Nor Akalili Ahmad, Lih Jang Tam, Pei Sean Goh, Nurfirzanah Azman, Ahmad Fauzi Ismail, Khairulnadzmi Jamaluddin, Gangasalam Arthanareeswaran
Summary: In this study, a thin film composite (TFC) reverse osmosis (RO) membrane with high long-term stability and antifouling properties was developed by spray coating the polyamide (PA) layer with oppositely charged titania nanosheets (TNS). The manufactured membranes showed improved permeability and radionuclide rejection, making them suitable for treating radionuclide-containing wastewater. The findings highlight the potential of tailored TFC RO membranes in the treatment of radioactive wastewater.
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
(2023)
Article
Multidisciplinary Sciences
Noor Fauziyah Ishak, Nur Hidayati Othman, Najihah Jamil, Nur Hashimah Alias, Fauziah Marpani, Munawar Zaman Shahruddin, Lau Woei Jye, Ahmad Fauzi Ismail
Summary: Modifying polymeric membranes using ZIF-8 functionalized-2D nanofillers showed improved gas permeability and selectivity performance. The rGO/ZIF-8 and MoS2/ZIF-8 nanofillers were successfully synthesized and characterized. Addition of 10 wt% of each nanofiller to the PES solution resulted in MMMs with enhanced thermal stability. Compatibility between the 2D nanofillers and PES matrix was confirmed by FTIR and XRD analysis. The obtained MMMs exhibited significantly improved gas separation properties, demonstrating the potential of using 2D nanofillers for high-performance membranes.
PERTANIKA JOURNAL OF SCIENCE AND TECHNOLOGY
(2023)
Article
Engineering, Environmental
Nurul Syazana Fuzil, Nur Hidayati Othman, Nur Hashimah Alias, Fauziah Marpani, Muhammad Shafiq Mat Shayuti, Munawar Zaman Shahruddin, Mohd Rizuan Mohd Razlan, Norazah Abd Rahman, Woei Jye Lau, Mohd Hafiz Dzarfan Othman, Ahmad Fauzi Ismail, Tutuk Djoko Kusworo, Anwar Ul-Hamid
Summary: In this study, the performance of membrane distillation (MD) was improved by coating MoS2-TiO2 on a PVDF-based hollow fiber membrane. The MoS2-TiO2/PP20 membrane showed enhanced hydrophobicity and porosity, leading to significantly improved MD performances. This work suggests that the MoS2-TiO2 coating can overcome the typical permeability/rejection rate trade-off effect and play a significant role in enhancing MD performances.
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
(2023)
Review
Engineering, Environmental
Nur Fajrina, Norhaniza Yusof, Ahmad Fauzi Ismail, Farhana Aziz, Muhammad Roil Bilad, Meshel Alkahtani
Summary: This article summarizes recent developments in membrane technology tailored for biogas upgrading, including the structure and classification of membrane materials as well as effective approaches to overcome the trade-off between permeability and selectivity. Additionally, other challenges are comprehensively discussed, and future research required to tackle biogas upgrading issues is projected.
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
(2023)