期刊
MACROMOLECULAR MATERIALS AND ENGINEERING
卷 302, 期 11, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/mame.201700218
关键词
oil-water separation; PDMS; polyester (PET); polypropylene (PP); superhydrophobicity
资金
- Korea Ministry of Environment as Global Top Project [RE201606134]
- National Research Foundation of Korea [2013R1A6A3A03057669] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
The surfaces of commercially available polyester (PET) and polypropylene (PP) are superhydrophobically modified via the deposition of polydimethylsiloxane (PDMS)-coated SiO2 nanoparticles (P-SiO2) and PDMS binder. The adhesion of P-SiO2 is stronger on PET than on PP due to a stronger chemical interaction between PET and PDMS, which is attributed to the higher surface energy of PET than PP. The waterproof ability and oil separation rate of the P-SiO2-coated PET (dip-PET) membranes are studied as a function of membrane thickness, and the influence of oil viscosity on the oil separation efficiency is investigated. Optimal membrane thickness should be selected in a given environment for the facile oil-water separation and the dip-PET membrane is chemically stable and can be used repetitively for oil-water separation. Finally, an automated prototype instrument is introduced for the dip-coating process. It is suggested that our dip-PET is a promising solution for oil-water separation in real-world oil-spill applications.
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