Open Cell Aerogel Foams via Emulsion Templating

The water-in-oil emulsion-templating method is used in this work for fabrication of open cell aerogel foams from syndiotactic polystyrene (sPS). A surfactant-stabilized emulsion is prepared at 60-100 degrees C by dispersing water in a solution of sPS in toluene. sPS gel, formed upon cooling of the emulsion to room temperature, locks the water droplets inside the gel. The gel is solvent exchanged in ethanol and then dried under supercritical condition of carbon dioxide to yield the aerogel foams. The aerogel foams show a significant fraction of macropores with a diameter of a few tens of micrometers, defined as macrovoids that originated from the emulsified water droplets. In conjunction, customary macro pores of diameter 50-200 nm are derived from sPS gels. The macrovoids add additional openness to the aerogel structures. This paper evaluates the structural characteristics of the macrovoids, such as diameter distribution, macrovoid interconnect density, and skin layer density, in conjunction with the final aerogel foam properties.