期刊
KINETICS AND CATALYSIS
卷 58, 期 2, 页码 140-146出版社
MAIK NAUKA/INTERPERIODICA/SPRINGER
DOI: 10.1134/S0023158417020057
关键词
liquid-phase acetylene hydrogenation; palladium catalyst; doping of catalysts; Pd-Ga; Pd-Zn; Pd-Ag catalysts
Pd/Sibunit and Pd-M/Sibunit (M = Ga, Zn, or Ag) catalysts have been synthesized, and their catalytic properties in liquid-phase acetylene hydrogenation have been investigated. Doping of the palladium catalyst with a metal M leads to the formation of the Pd2Ga, PdZn, or Pd0.46Ag0.54 bimetallic compound. The bimetallic particles are much smaller (1.6-2.0 nm) than the monometallic palladium particles (4.0 nm). Doping with zinc raises the ethylene selectivity by 25% without affecting the activity of the catalyst. Specific features of the effect of each of the dopants on palladium are reported.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据